Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
The papers by Borchers,[39] Doeltz,[40] Guillemain,[41] and
Hutchings[42] may profitably be studied in connection with the
reactions involved in lime-roasting. The conclusion will be, however,
that their precise nature has not yet been determined. In view of the
great interest that has been awakened by this new departure in the
metallurgy of lead, it is to be expected that much experimental work
will be devoted to it, which will throw light upon its principles, and
possibly develop it from a mere process of desulphurization into one
which will yield a final product in a single operation.
PART VI
OTHER METHODS OF SMELTING
THE BORMETTES METHOD OF LEAD AND COPPER SMELTING[43]
BY ALFREDO LOTTI
(September 30, 1905)
It is well known that, in order to obtain a proper fusion in lead
and copper ore-smelting, it is not only advantageous, but often
indispensable, that a suitable proportion of slag be added to the
charge. In the treatment of copper matte in the converter, the total
quantity of slag must be resmelted, inasmuch as it always retains a
notable quantity of the metal; while in the smelting of lead ore in the
blast furnace, the addition of slag is mainly intended to facilitate
the operation, avoiding the use of strong air pressure and thus
diminishing the loss of lead. The proportion of slag required sometimes
amounts to 30 to 35 per cent. of the weight of the ore.
Inasmuch as the slag is usually added in lump form, cold, its original
heat (about 400 calories per kilogram) is completely lost and an
intimate mixture with the charge cannot be obtained. For this reason, I
have studied the agglomeration of lead and copper ores with fused slag,
employing a variable proportion according to the nature of the ore
treated. In the majority of cases, and with some slight modifications
in each particular case, by incorporating the dry or slightly moistened
mineral with the predetermined quantity of liquid slag, and by rapidly
stirring the mixture so as to secure a proper subdivision of the slag
and the mineral, there is produced a spongy material, largely composed
of small pieces, together with a simultaneous evolution of dense fumes
of sulphur, sulphur dioxide, and sulphur trioxide. By submitting this
spongy material to an air blast, the sulphur of the mineral is burned,
the temperature rising in the interior of the mass to a clear red
heat. Copious fumes of sulphur dioxide and trioxide are given off,
and at times a yellowish vapor of sulphur, which condenses in drops,
especially if the ore is pyritous.
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