Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
At the end of from one to three hours, according to the quantity of
sulphur contained in the material under treatment and the amount of the
air pressure, the desulphurization of the ore, so far as it has come
in contact with the air, is completed, and the mass, now thoroughly
agglomerated, forms a spongy but compact block. It is then only
necessary to break it up and smelt it with the requisite quantity of
flux and coke. The physical condition of the material is conducive to
a rapid and economical smelting, while the mixture of the sulphide,
sulphate and oxide leads to a favorable reaction in the furnace.
In employing this method, it sometimes happens that ores rich in
sulphur produce during the smelting a little more matte than when the
ordinary system of roasting is employed. In such instances, in order
to avoid or to diminish the cost of re-treatment of the matte, it is
best to agglomerate a portion thereof with the crude mineral and the
slag. This has the advantage of oxidizing the matte, which acts as a
ferruginous flux in the smelting.
The system described above leads to considerable economy, especially
in roasting, as the heat of the scoria, together with that given off
in the combustion of the sulphur, is almost always sufficient for the
agglomeration and desulphurization of the mineral; while, moreover, it
reduces the cost of smelting in the blast furnace. Although the primary
desulphurization is only partial (about 50 per cent.), it continues
in the blast furnace, since the mineral, agglomerated with the slag,
assumes a spongy form and thereby presents an increased surface to the
action of the air. The sulphur also acts as a fuel and does not produce
an excessive quantity of matte.
The system will prove especially useful in the treatment of
argentiferous lead ore, since, by avoiding the calcination in a
reverberatory furnace, loss of silver is diminished. It appears,
however, that, contrary to the reactions which occur in the
Huntington-Heberlein process, a calcareous or basic gangue is not
favorable to this process, if the proportion be too great.
The following comparison has been made in the case of an ore containing
62 to 65 per cent. of lead, 16 to 17 per cent. sulphur, 10 to 11 per
cent. zinc, 0.4 per cent. copper, and 0.222 per cent. silver, in which
connection it is to be remarked that, in general, the less zinc there
is in the ore the better are the results.
[Illustration: FIG. 21.—Elevation and Plan of Converting Chambers.]
_Ordinary Method._—Roast-reduction. Cost per 1000 kg. of crude ore:
1. Roasting in reverberatory furnace:
Labor $0.70
Fuel 1.50
Repairs and supplies .05
————- $2.25
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