Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
Immediately the copper dross is skimmed off the heat is raised
considerably, and very soon a tin (and arsenic, if present) skimming
appears. It is quite “dry” and may be removed in an hour or so. It is a
very small skimming, and the tin, not being worth saving, is put with
the copper dross.
The temperature is now raised again and antimony soon shows in black,
boiling, oily drops, gathering in time into a sheet covering the
surface of the lead. When the skimming is about ½-inch thick, slaked
lime, ashes, or fine coal is thrown on and stirred in. The dross soon
thickens up and may be skimmed off easily. This operation is repeated
until all antimony is eliminated. Constant stirring of the charge is
necessary. The addition of litharge greatly facilitates the removal
of antimony; either steam or air may be blown on the surface of the
metal to hasten oxidation, though they have anything but a beneficial
effect on the furnace lining. From time to time samples of the dross
are taken in a small ladle, and after setting hard the sample is broken
in two. A black vitreous appearance indicates plenty of antimony yet
in the charge. Later samples will look less black, until finally a few
yellowish streaks are seen, being the first appearance of litharge.
When all antimony is out the fracture of a sample should be quite
yellow and the grain of the litharge long, a short grain indicating
impurities still present, in which case another skimming is necessary.
The analysis of a representative sample of antimony dross was as
follows:
PbO = 78.11 per cent.
Sb₂O₄ = 8.75 ” ”
As₂O₃ = 2.18 ” ”
CuO = 0.36 ” ”
CaO = 1.10 per cent.
Fe₂O₃ = 0.42 ” ”
Al₂O₃ = 0.87 ” ”
Insol. = 4.10 ” ”
Antimony dross is usually kept separate and worked up from time to
time, yielding hard antimonial lead, used for type metal, Britannia
metal, etc.
Public-domain text, read in full here on John Shaqi.
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