Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
_Desilverization._—The softening being completed the charge is tapped
and run to a kettle or pan of cast iron or steel, holding, when
conveniently full, some 12 or 13 tons. The lead falling into the
kettle forms a considerable amount of dross, which is skimmed off and
returned to the softening furnace. By cooling down the charge until
it nearly “freezes” an additional copper skimming is obtained, which
also is returned to the softener. The kettle is now heated up to the
melting point of zinc, and the zinc charge, determined by the gold
and silver contents of the kettle, is added and melted. The charge
is stirred, either by hand or steam, for about an hour, after which
the kettle is allowed to cool down for some three hours and the first
zinc crust taken off. When the charge is skimmed clean a sample of the
bullion is taken for assay, and while this is being done the kettle is
heated again for the second zinc charge, which is worked in the same
way as the first; sometimes a third addition of zinc is necessary. The
resulting crusts are kept separate, the second and third being added
to the next charge as “returns,” allowing 3 lb. of zinc in returns as
equal to 1 lb. of fresh zinc. An alternative method is to take out gold
and silver in separate crusts, in which case the quantity of zinc first
added is calculated on the gold contents of the kettle only. The method
of working is the same, though subsequent treatment may differ in that
the gold crusts are cupeled direct.
As to the quantity of zinc required:
1. Extracting the gold with as little silver as possible, the following
figures were obtained:
Total Gold— Au.
In kettle 300 oz. │ 1 lb. zinc takes out 1.00 oz.
” ” 200 ” │ ” ” ” ” 1.00 ”
” ” 150 ” │ ” ” ” ” 0.79 ”
” ” 100 ” │ ” ” ” ” 0.59 ”
” ” 60 ” │ ” ” ” ” 0.45 ”
2. Silver zinking gave the following general results with 11-ton
charges:
Total Silver—
In kettle 1,450 oz. │ 1 lb. zinc takes out 5.6 oz.
” ” 1,200 ” │ ” ” ” ” 4.1 ”
” ” 930 ” │ ” ” ” ” 3.8 ”
” ” 755 ” │ ” ” ” ” 3.5 ”
” ” 616 ” │ ” ” ” ” 3.4 ”
” ” 460 ” │ ” ” ” ” 2.6 ”
3. Extracting gold and silver together:
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