Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
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TOTAL CONTENTS OF KETTLE │ 1 LB. ZINC TAKES OUT
AU. OZ. │ AG. OZ. │ AU. OZ. │ AG. OZ.
────────────┼──────────────┼─────────────┼────────
494 │ 3,110 │ 0.59 │ 3.60
443 │ 1,883 │ 0.64 │ 2.80
330 │ 2,417 │ 0.45 │ 3.34
204 │ 1,638 │ 0.36 │ 2.86
143 │ 1,330 │ 0.28 │ 2.65
123 │ 1,320 │ 0.23 │ 2.54
────────────┴──────────────┴─────────────┴────────
It will be noticed that in each case the richer the bullion the greater
the extractive power of zinc. Experiments made on charges of rich
bullion showed that the large amount of zinc called for by the table in
use was unnecessary, and 250 lb. was fixed on as the first addition of
zinc. On this basis an average of 237 charges gave results as follows:
───────────────────┬───────────┬──────────────────────
TOTAL CONTENTS │ ZINC USED │ 1 LB. ZINC TAKES OUT
AU. OZ. │ AG. OZ. │ LBS. │ AU. OZ. │ AG. OZ.
────────┼──────────┼───────────┼───────────┼──────────
520 │ 1,186 │ 507.5 │ 1.27 │ 2.91
────────┴──────────┴───────────┴───────────┴──────────
The zinc used was that necessary to clean the kettle, added as follows:
1st, 250 lb.; 2d (average), 127 lb.; 3d (average), 57 lb. In 112 cases
no third addition was required. From these figures it appears that in
the earlier work the zinc was by no means saturated.
_Refining the Lead._—Gold and silver being removed, the lead is
siphoned off into the refining kettle and the fire made up. In about
four hours the lead will be red hot, and when hot enough to burn zinc,
dry steam, delivered by a ¾ in. pipe reaching nearly to the bottom of
the kettle, is turned on. The charge is stirred from time to time and
wood is fed on the top to assist dezinking and prevent the formation
of too much litharge. In three to four hours the lead will be soft and
practically free from zinc. When test strips show the lead to be quite
soft and clean, the kettle is cooled down and the scum of lead and
zinc oxides skimmed off. In an hour or so the lead will be cool enough
for molding; the bar should have a yellow luster on the face when set;
if the lead is too cold it will be white, if too hot a deep blue. The
refining kettles are subjected to severe strain during the steaming
process, and hence their life is uncertain—an average would be about 60
charges; the zinking kettles, on the other hand, last very much longer.
Good steel kettles (if they can be obtained) are preferable to cast
iron.
Public-domain text, read in full here on John Shaqi.
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