Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
The electrical resistance in the tanks was found to be greater than
had been calculated for the same solution, plus an allowance for
loss of voltage in the contacts and conductors. This is partly, at
least, due to the resistance to free motion of the electrolyte, in
the neighborhood of the anode, offered by a layer of slime which may
be anything up to ½ in. thick. During electrolysis, the SiF₆ ions
travel toward the anodes, and there combine with lead. The lead and
hydrogen travel in the opposite direction and out of the slime; but
there are comparatively few lead ions present, so that the solution
in the neighborhood of the anodes must increase in concentration and
tend to become neutral. This greater concentration causes an e.m.f. of
polarization to act against the e.m.f. of the dynamo. This amounted
to about 0.02 volt for each tank. The greater effect comes from the
greater resistance of the neutral solution with which the slime is
saturated. There is, consequently, an advantage in working with rather
thin anodes, when the bullion is impure enough to leave slime sticking
to the plates. A compensating advantage is found in the increased ease
of removing the slime with the anodes, and wiping it off the scrap in
special tanks, instead of emptying the tanks and cleaning out, as is
done in copper refineries.
It is very necessary to have adequate apparatus for washing solution
out of the slime. The filter first used consisted of a supported
filtering cloth with suction underneath. It was very difficult to
get this to do satisfactory work by reason of the large amount of
fluosilicate to be washed out with only a limited amount of water.
At the present time the slime is first stirred up with the ordinary
electrolyte several times, and allowed to settle, before starting to
wash with water at all. The Trail plant produces daily 8 or 10 cu. ft.
of anode residue, of which over 90 per cent. by volume is solution.
The evaporation from the total tank surface of something like 400 sq.
ft. is only about 15 cu. ft. daily; so that only a limited amount of
wash-water is to be used—namely, enough to replace the evaporated
water, plus the volume of the slime taken out.
Public-domain text, read in full here on John Shaqi.
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