Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
This plant, at South Chicago, Ill., refines base lead bullion. It
comprises four reverberatory furnaces, of which one takes a charge of
100 tons, one 80 tons, and the other two 30 tons each; one of the small
furnaces is being torn down, and a 120 ton furnace is to be built in
its place. The furnaces are fired with coal from Southern Illinois,
which contains 11 per cent. of ash.
In softening the bullion, the time for each charge is 10 hours. The
first portion tapped consists of dross rich in copper, which is
followed by antimonial skimmings and litharge.
The copper dross is melted up in a small reverberatory furnace,
together with galena from Wisconsin (containing 80 per cent. lead),
for work-lead and lead-copper matte, the latter containing about 35
per cent. of copper; this matte is enriched to 55 per cent. copper
by the addition of roasted matte, and is finally worked up for crude
copper (95 per cent.) in a reverberatory furnace. All the copper so
produced is used in the parting process for precipitating the silver.
The antimonial skimmings are smelted in a reverberatory furnace,
together with coke cinder, for lead and a slag rich in antimony, which
is reduced to hard lead (27 per cent. antimony, 0.5 per cent. copper,
0.5 per cent. arsenic) in a small blast furnace, 14 ft. high, which has
8 tuyeres.
The softened lead is tapped off into cast-iron desilverizing pots,
which usually outlive 200 charges; in isolated cases as many as
300. For desilverizing, zinc from Pueblo, Colo., is added in two
instalments, being mixed in by means of a Howard stirrer. After the
first addition there remains in the lead 7 oz. of silver per ton;
after the second only 0.2 oz. The first scum is pressed in a Howard
press and distilled; the second is ladled off and is added to the next
charge. The Howard stirrer is driven by a small steam engine suspended
over the kettle; the Howard press by compressed air.
For distilling zinc scum, 12 Faber du Faur tilting retorts, heated with
petroleum residue, are used. The argentiferous lead (with 9.6 per cent.
silver) is transferred from the retort to a pan lined with refractory
brick, which is wheeled to the cupelling hearth and raised by means of
compressed-air cylinders, so as to empty its molten contents through a
short gutter upon the cupelling hearth. The cupelling hearths are of
the water-cooled English type, and are heated by coal with under-grate
blast. The cast-iron test rings, with reinforcing ribs, are made in two
pieces, slightly arched and water-cooled; they are rectangular, with
rounded corners, and are mounted on wheels. The material of the hearth
is marl.
Argentiferous lead is added as the operation proceeds, and finally the
doré bullion is poured from the tilted test into thick bars (1100 oz.)
for parting.
Public-domain text, read in full here on John Shaqi.
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