Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
The desilverized lead is refined in charges of 28 tons (4 to 5 hours)
and 80 to 90 tons (8 to 10 hours), introducing steam through four to
eight half-inch iron pipes. The first skimmings contain a considerable
proportion of antimony and are therefore added to the charge when
reducing the antimonial slags in the blast furnace. The litharge is
worked up in a reverberatory furnace for lead of second quality. The
refined lead is tapped off into a kettle, from which it is cast into
bars through a siphon.
The parting of the doré bullion is carried out in tanks of gray cast
iron, in which the solution is effected with sulphuric acid of 60 deg.
B. The acid of 40 deg. B. condensed from the vapors is brought up to
strength in leaden pans. In a second larger tank, which is slightly
warmed, a little gold deposits from the acid solution of sulphates.
The solution is then transferred (by the aid of compressed air) to the
large precipitating tank, and diluted with water. It is here heated
with steam, and the silver is rapidly precipitated by copper plates
(125 plates 18 × 8 × 1 in.) suspended in the solution from iron hooks
covered with hard lead. After the precipitation, the vitriol lye is
siphoned off, the silver is washed in a vat provided with a false
bottom, is removed with a wooden shovel, and is pressed into cakes 10 ×
10 × 6 in.
The refining is finished on a cupelling hearth fired with petroleum
residue, adding saltpeter, and removing the slag by means of powdered
brick. After drawing the last portion of slag the silver (0.999 fine)
is kept fused under a layer of wood-charcoal for 20 minutes, and is
then cast into iron molds, previously blackened with a petroleum flame.
The bars weigh about 1100 oz.
The gold is boiled with several fresh portions of acid, is washed and
dried, and finally melted up with a little soda in a graphite crucible.
It is 0.995 fine.
The lye from the silver precipitation, after clearing, is evaporated
down to 40 deg. B. in leaden pans by means of steam coils, and is
transferred to crystallizing vats. The first product is dissolved
in water, the solution is brought up to 40 deg. B. strength, and is
allowed to crystallize. The purer crystals so obtained are crushed, and
are washed and dried in centrifugal apparatus; they are then sifted and
packed in wooden casks in two grades according to the size of grain.
The very fine material goes back into the vats. From the first strongly
acid mother liquor, acid of 60 deg. B. is prepared by concentrating in
leaden pans, and this is used for the parting operation.
THE EAST HELENA PLANT OF THE AMERICAN SMELTING AND REFINING COMPANY[57]
BY O. PUFAHL
(April 28, 1906)
The monthly production of these works is about 1500 tons of base
bullion (containing 150 oz. Ag and 4 to 6 oz. Au per ton), and 200 tons
of 45 per cent. copper matte. The base bullion is shipped to South
Chicago, the matte to Pueblo.
Public-domain text, read in full here on John Shaqi.
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