Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
This feature sharply distinguishes it from other known processes.
It is true that in previous processes (compare the Tarnowitz
reverberatory-furnace process, the roasting process used at
Munsterbusch near Stolberg, and others) the lead ore was mixed with
limestone or dolomite (which are converted into oxides in the early
stage of the roast) and the heat was alternately raised and lowered;
but in all cases only a surface action of the air was produced, the air
supply being provided simply by the furnace draft. Passing air through
the mass cooled down, as indicated above, leads to the important
economic advantages of reducing the fuel consumption, the losses of
lead, the manual labor (raking) and the dimensions of the roasting
apparatus.
In order to carry out the process of this invention, the powdered ore
is intimately mixed with a quantity of alkaline earth oxide, _e.g._,
calcium oxide, corresponding to its sulphur content; if the ore
already contains alkaline earth, the quantity to be added is reduced
in accordance. The mixture is heated to bright-red heat (700 deg. C.)
in the reverberatory furnace, in a strongly oxidizing atmosphere, is
then allowed to cool down to dark-red heat (500 deg. C.), also in
strongly oxidizing atmosphere, is transferred to a vessel called the
“converter,” and atmospheric air is passed through at a slight pressure
(the inventors have found a blast corresponding to 35 to 40 cm. head
of water suitable).[19] The heat liberated is quite sufficient to keep
the charge at the reaction temperature, but, if desired, hot blast may
also be used. The mixture sinters together, and (while sulphurous acid
gas escapes) it is gradually converted into a mass consisting of lead
oxide, gangue and calcium sulphate, from which the lead is extracted in
the metallic form, by any of the known methods, in the shaft furnace.
The operation is concluded as soon as the mass, by continued sintering,
has become impermeable to the blast. If the operation is properly
conducted, the gas escaping contains only small quantities of volatile
lead compounds, but on the other hand up to 8 per cent. by volume of
sulphur dioxide. This latter can be collected and further worked up.
“In place of the oxide of an alkaline earth, ferrous oxide (FeO) or
manganous oxide (MnO) may also be used.”
According to the reports on the practice of this process which have
been published,[20] conical converters of about 1700 mm. (5 ft. 6
in.) upper diameter and 1500 mm. (5 ft.) depth are used in Australian
works. At a new plant at Port Pirie (Broken Hill Proprietary Company)
converters 2400 mm. (7 ft. 10 in.) in diameter and 1800 mm. (5 ft.
11 in.) deep have been installed. These latter will hold a charge of
about eight tons. In the lower part of these converters, at a distance
of about 600 mm. (2 ft.) from the bottom, there is placed an annular
perforated plate, and upon this a short perforated tube, closed above
by a plate having only a limited number of holes.
Public-domain text, read in full here on John Shaqi.
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