Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
No details have been published with regard to the European
installations. The general information which the Metallurgische
Gesellschaft[21] placed at my disposal upon request some years ago,
for use in my lecture courses, was restricted to data regarding the
consumption of fuel and labor in roasting and smelting the ores, which
was figured at about one-third or one-half of the consumption in the
former processes, to the demonstration of the large output of the
comparatively small converters, and to the reduced size of the roasting
plant as the result. But the European establishments which introduced
this process were bound by the owners of the patents, notwithstanding
the protection afforded by the patents, to give no information whatever
regarding the process to outsiders, and not to allow any inspection of
the works.
On the other hand, a great deal appeared in technical literature
which was calculated to excite curiosity. Moreover, as professor of
metallurgy, it was my duty to instruct my pupils concerning this
process among others, and it was therefore very gratifying to me
that one of the students in my laboratory took a special interest in
the treatment of lead ore. I gave him opportunity to install a small
converter, in order to carry out the process on a small scale, and
in spite of the slender dimensions of the apparatus the very first
experiments gave a complete success.
However, I could not harmonize the explanation of the process given by
the inventors with the knowledge which I had acquired in my many years’
practical experience in the manufacture of peroxides. It is clear from
the patent specification that in the roasting operation at 700 deg.
C. a compound must be formed which functions as an excellent oxygen
carrier, for on cooling to 500 deg. C. the further oxidation then
proceeds to the end not only without any external application of heat,
but even with vigorous evolution of heat. No more striking instance
than this could be desired by the theorists who have of recent years
again become so enthusiastic over the idea of catalysis. Huntington
and Heberlein regarded calcium peroxide as the oxygen carrier, but that
is a compound which cannot exist at all under the conditions which
obtain in their process. The peroxides of the alkaline earths are so
very sensitive that in preparing them the small quantities of carbon
dioxide and water must be extracted carefully from the air, and yet
in the process, in an atmosphere pregnant with carbon dioxide, water,
sulphurous acid, etc., calcium peroxide, the most sensitive of the
whole group, is supposed to form! This could not be.
Public-domain text, read in full here on John Shaqi.
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