Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
The only compounds known as oxygen carriers, and capable of existing
under the conditions of the process, are calcium plumbate and plumbite.
I have emphasized this point from the first in my lectures on
metallurgy, when dealing with the Huntington-Heberlein process, and, in
point of fact, this assumption has since been proved to be correct by
the work of L. Huppertz, one of my students.
During my practical activity (1879-1891) I had prepared barium peroxide
and lead peroxide in large quantities on a manufacturing scale, the
last-mentioned through the intermediate formation of plumbites and
plumbates:
2NaOH + PbO + O = Na₂PbO₃ + H₂O
or:
4NaOH + PbO + O = Na₄PbO₄ + 2H₂O.
An experiment made in this connection showed that calcium plumbate is
formed just as readily from slaked lime and litharge as the sodium
plumbates above. Litharge is an intermediate product, produced in
large quantities in lead works, and must in any case be brought
back into the process. If, then, the litharge is roasted at a low
temperature with slaked lime, the roasting of the galena could perhaps
be entirely avoided by introducing that ore together with calcium
plumbate into the converter, after the latter had once been heated up.
Mr. Huppertz undertook the further development of this process, but I
have no information on the later experimental results, as he placed
himself in communication with neighboring lead works for the purpose
of continuing his investigation, and has not since then given me any
precise data. I will therefore confine myself to the statement that
the fundamental idea for the experiments, which Mr. Huppertz undertook
at my suggestion, was the following:
To dispense with the roasting of the galena, which is necessary
according to Huntington and Heberlein; in other words, to convert
the galena by direct blast, with the addition of calcium plumbate,
the latter being produced from the litharge which is an unavoidable
intermediate product in the metallurgy of lead and silver. (Borchers,
“Elektrometallurgie,” 3d edition, 1902-1903, p. 467.)
This alone would, of course, have meant a considerable simplification
of the roast, but the problem of the roasting of galena has been solved
in a better way by A. Savelsberg, of Ramsbeck, Westphalia, who has
determined the conditions for directly converting the galena with the
addition of limestone and water and without previous roasting. He has
communicated the following information regarding these conditions:
Public-domain text, read in full here on John Shaqi.
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