Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
In order that, in blowing the air through the mixture of ore and
limestone, an alteration of the mixture may not take place owing to the
lighter particles of the limestone being carried away, it is necessary
(quite at variance with the processes in use hitherto, in which for the
sake of economy stress is laid on the precaution of charging the ore
as dry as possible into the apparatus) to add a considerable quantity
of water to the charge before introducing it into the converter. The
water serves this purpose perfectly, also preventing any change in
the mixture of ore and limestone, which invariably occurs if the ore
is used dry. The water, moreover, exerts a very beneficial action
in the process, inasmuch as it aids materially in the formation and
temporary retention of sulphuric acid, which latter then, by its
oxidizing action, greatly enhances the reaction and consequently the
desulphurization of the ore. Furthermore, the water tends to moderate
the temperature in the charge by absorbing heat in its volatilization.
In carrying out the process the converter must not be filled entirely
all at once, but first only in part, additional layers being charged
in gradually in the course of the operation. In this way a uniform
progress of the reaction in the mass is secured.
The following mode of procedure is advantageously adopted: A small
quantity of glowing fuel (coal, coke, etc.) is introduced into the
converter, which is provided at the bottom with a grate (perforated
sheet iron), the grate being first covered with a thin layer of crushed
limestone in order to protect it from the action of the red-hot coals
and ore. Upon this red-hot fuel a uniform layer of the wetted mixture
of crude ore and limestone is placed. When the surface of the first
layer has acquired a uniform red heat, a fresh layer is charged on,
and this is continued, layer by layer, until the converter is quite
full. While the layers are still being put on, the blast is passed in
at quite a low pressure, and only when the converter is entirely filled
is the whole force of the blast, at a rather greater pressure, turned
on. There then sets in a kind of slag formation, which, however, is
preceded by a very vigorous desulphurization. After the termination of
the process, which can be recognized by the fact that vapors cease to
be evolved, and that the surface of the ore becomes hard, the converter
is tipped over, and the desulphurized mass drops out as a solid cone of
slag, which is then suitably broken up for the subsequent smelting in
the shaft furnace.
Savelsberg explains the reaction of this process as follows:
“1. The particles of limestone act mechanically, gliding in between the
particles of lead ore and separating them from one another. In this
way a premature sintering is prevented, and the whole mass is rendered
loose and porous.
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