Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
If, in place of lime, we take an equivalent weight of pure calcium
carbonate and intimately mix it with ore, we obtain just the same
action, only it takes a little longer to start it. Once started, it
is almost as vigorous and rapid, and with the same results. It does
not seem correct to assume (as is usually done) that the carbonate has
first to be decomposed by heat, the lime then coming into action. The
reaction commences in so short a time and while the charge is still
so cool, that no appreciable driving off of CO₂ by heat only can
have taken place. The main liberation of the CO₂ occurs during the
vigorous exothermic oxidation of the mixture, and is coincident with
the conversion of the CaO into CaSO₄.
If, in place of lime or its carbonate, we use a corresponding quantity
of pure calcium sulphate and mix it with the ore, we see very energetic
roasting in this case also, with copious evolution of sulphur dioxide,
only it is much more energetic and rapid and occurs at a lower
temperature than in the case of a companion charge of ore alone.
It is very easily demonstrated that the CaSO₄ in contact with the
still unoxidized ore (whether it has been introduced ready made or has
been formed from lime or limestone added) greatly assists the further
roasting, in acting as a “carrier” and enabling calcination to take
place more rapidly and easily and at a lower temperature than would
otherwise be the case.
The result of these experiments (whether we mix the ore with CaO,
CaCO₃, or CaSO₄) is that we arrive with great ease and rapidity
at a nearly dead-sweet roast. The lime is converted into sulphate, and
the lead partly to sulphate and partly to oxide. Two examples out of
several, both from the above ore, gave results as follows:
No. 1—Roasted with 20 per cent. CaCO₃ (= 11.2 per cent. CaO);
sulphide sulphur, 0.02 per cent.; sulphate sulphur, 9.30 per cent.;
total sulphur, 9.32 per cent.
No. 8—Roasted with 27.2 per cent. CaSO₄ (= 11 per cent. CaO);
sulphide sulphur, 0.05 per cent.; sulphate sulphur, 11.28 per cent.;
total sulphur, 11.33 per cent.
If these calcined products are now intimately mixed with additional
silica (in about the proportions used in the Huntington-Heberlein
process) and strongly heated, fritting is brought about and the sulphur
content is reduced by the decomposition of the sulphates by the silica.
Thus, the resultant material of experiment No. 1, above, when treated
in this manner with strong heat for three hours, was sintered to a mass
which was quite hard and stony when cold, and which contained 6.75
per cent. of total sulphur. Longer heating drives out more sulphur,
but a very long time is required; in furnaces, and on a large scale,
it is with great difficulty and cost that a product can be obtained
comparable with that which is rapidly and cheaply turned out from the
“converters” of the new process.
Public-domain text, read in full here on John Shaqi.
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