Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
To return to the Huntington-Heberlein process, working, for example,
on an ore more or less like the one given above, we may assume that,
during the comparatively short preliminary roast, the lime is all
rapidly converted into CaSO₄ and that some PbSO₄ is also formed
(but not much, as the mixture to be transferred from the furnace to
the converter requires not less than 6 to 8 per cent. of sulphur to
be still present as sulphide, in order that the following operation
may work at its best). As the blast permeates the mass, oxidation is
energetic; no doubt that CaSO₄ here plays a very important part
as a carrier of oxygen, in the same manner as we can see it act on a
scorifier or on the hearth of a furnace.
What the later reactions are does not seem so clear. They are quite
different from those on the scorifier or on the open hearth of a
furnace, and result in the rapid formation (in successive layers of
the mixture, from the bottom upward) of large amounts of lead oxide,
fluxing the silica and other constituents to a more or less slaggy
mass, which decomposes the sulphates and takes up the CaO into a
complex and easily fused silicate. It is true that, as a whole, the
contents of a well-worked converter are never very hot, but locally
(in the regions where the progressive reaction and decomposition from
below upward is going on) the temperature reached is considerable. This
formation of lead oxide is so pronounced at times that one may see in
the final product considerable quantities of pure uncombined litharge.
When the work is successful, the mass discharged from the converters
is a basic silicate of PbO, CaO, and oxides of other metals present,
and nearly all the sulphates have disappeared. A large piece of yellow
product (which was taken from a well-worked converter) contained only
1.1 per cent. of total sulphur.
It may be that calcium plumbate is formed and plays a part in these
reactions; but its presence would be difficult to prove, and its
formation and existence during these stages would not be easy to
explain. Neither does it seem necessary, as the whole thing appears to
be capable of explanation without it.
Public-domain text, read in full here on John Shaqi.
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