Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
Finally comes the Savelsberg patent, which is the simplest of all;
not only (like the Carmichael process) avoiding the preliminary roast
with its extra plant, but also not requiring the use of ready-made
CaSO₄, as it uses raw ore and limestone directly in the converter.
I have no knowledge as to actual results of this process; and, so
far as I am aware, nothing on the subject has been published. But
Professor Borchers evidently has some information about it, and
regards it as the most successful of the methods of carrying out the
new ideas. On the face of it, there seems no reason why it should not
attain all the results desired, as the chemical and physical actions
of the CaO, and of the CaSO₄ formed from it, should come into play
in the same manner and in the same order as in the original process;
as it is carried out in the identical converter used by Huntington
and Heberlein, the final reactions (as suggested above) will take
place under the same conditions as to continuous decomposition _under
considerable heat and pressure_, which I regard as the most vital part
of the whole matter.
It is well to emphasize again the fact that the idea, and the means of
obtaining these vital conditions, owe their origination to Huntington
and Heberlein.
THEORETICAL ASPECTS OF LEAD-ORE ROASTING[22]
BY C. GUILLEMAIN
(March 10, 1906)
It is well known that the process of roasting lead ores in
reverberatory furnaces proceeds in various ways according to the
composition of the ore in question. Thus in roasting a sulphide lead
ore rich in silica, one of the reactions is:
PbS + 3O = PbO + SO₂.
But this reaction is incomplete, for the gases which pass on in the
furnace are rich in SO₂ and in SO₃. And so it is found that
whatever lead oxide is formed passes over almost immediately into lead
sulphate, according to the reaction:
PbO + SO₂ + O = PbSO₄.
This reaction is the chief one which takes place. Whether the silicious
gangue serves as a catalyzer for the sulphur dioxide, or whether it
serves merely to keep the galena open to the action of the gases, the
end result of the roast is usually the formation of lead sulphate
according to the above reaction.
In the case of an ore rich in galena, a slow roast is essential, for it
is desired to have the following reaction take place during the latter
part of the roast:
PbS + 3PbSO₄ = 4PbO + 4SO₂.
Now, if the heating were too rapid, not enough lead sulphate would be
found to react with the unaltered galena. The quick roasting of a rich
ore would result in the early sintering of the charge, and sintering
prevents the further formation of lead sulphate. Whether this sintering
(which takes place so easily and which is so harmful in the latter part
of the process) is due to the low melting point of the lead sulphide,
whether the heat evolved by the reaction
PbS + 3O = PbO + SO₂
Public-domain text, read in full here on John Shaqi.
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