Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
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Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
The substitution of a large balloon, having a capacity of about 2
litres, in place of the small vessel of Flandin and Danger's apparatus,
is to be recommended as doing away with the necessity of evaporation; an
operation which invariably causes a loss of substance. The apparatus,
modified in this manner, is the most delicate in use for the detection
of mercury.
DETECTION OF PHOSPHORUS.
ORFILA'S METHOD.
The solid substances found in the alimentary canal are mechanically
separated from the fluids present by means of a linen cloth. They are
then examined by aid of a magnifying glass, and any fragments of
phosphorus found separated and preserved under water. If none are
discovered, the presence of phosphorescent vapors may possibly be
detected by examining the materials in the dark. In any case, a portion
of the suspected materials should be treated with nitrate of silver: in
presence of phosphorus the materials acquire, first, a reddish-brown,
then, a black color. The remaining portion is spread upon a shovel and
heated: a white flame, burning at various points of the mass, and
originating from the combustion of phosphorus, is observed, if this body
be contained in the substances under examination. This method is
evidently far from perfect.
MITSCHERLICH'S METHOD.
Mistcherlich's method is based upon the luminosity of the vapors of
phosphorus. The suspected materials are moistened with dilute sulphuric
acid, and heated, in a flask communicating with a glass worm which
passes through a glass cooler into a receiver. If the apparatus is
placed in the dark, and the materials contain phosphorus, luminous
vapors will be observed in the flask and receiver. When the quantity of
the poison present is considerable, the phosphorous acid formed can be
collected and its properties tested.
DUSART'S METHOD, AS MODIFIED BY BLONDLOT.
[Illustration: Fig. 10.]
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