Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
Dusart's process takes advantage of the facility with which hydrogen
combines with phosphorus. The substances under examination are placed
between two asbestus stoppers in a tube, one end of which tapers to a
point, and a current of pure hydrogen conducted over them. In presence
of phosphorus the evolved gas will burn with a green flame, and, upon
bringing this in contact with a porcelain plate, red spots will be
deposited upon the latter. _Blondlot_ prefers to introduce the suspected
materials into the flask in which the hydrogen is generated. He employs
the apparatus represented in Fig. 10: _a_ is a flask for evolving
hydrogen; _b_ is a U tube, filled with fragments of pumice stone which
are saturated with a concentrated solution of potassa; _c_ is a Mohr
clamp; _d_ a screw-clamp; _e_ a platinum jet. This jet is necessary in
order to avoid a yellow coloration of the flame by the soda contained in
the glass. Pure hydrogen is at first evolved, in order to ascertain that
the flame is colorless and red spots are not produced when it is
intersected by a cold plate. The purity of the reagents used having thus
been confirmed, the clamp _d_ is closed until the acid is forced back
into _f_; and the materials to be examined are then added to the fluid.
Upon opening the clamp the liquid passes from _f_ into _a_, and the
evolution of gas recommences. The gas is then ignited: the flame
possesses the characteristic properties mentioned above, if the
suspected substances contain phosphorus.
METHOD PROPOSED BY FRESENIUS AND NEUBAUER.
According to this method, the materials are brought into a flask
provided with a doubly-perforated stopper, and water, acidulated with
sulphuric acid, added. The flask is then heated over a water-bath, and a
current of carbonic acid conducted through the mixture for at least two
hours. The gas, on leaving the flask, passes into a solution of nitrate
of silver. Should no precipitate form in this solution, the absence of
free phosphorus is established, for, were this body present, a portion
would be volatilized, and a black precipitate, consisting of phosphide
of silver, together with phosphoric acid, produced. The formation of a
black precipitate is, however, not necessarily a proof of the presence
of phosphorus. In order to conclusively determine the character of the
precipitate, it is collected on a filter and examined by the method of
Dusart and Blondlot.
This process has given result in cases where none were obtained by
Mistcherlich's method. It possesses, moreover, an advantage over the
latter process, in not being influenced by the presence of foreign
bodies; whereas, in Mistcherlich's method, some time must elapse before
the luminosity of the vapors becomes apparent if ether or alcohol is
contained in the solutions, and this phenomenon totally fails to appear
in presence of oil of turpentine.
DETECTION OF PHOSPHORUS BY THE USE OF BISULPHIDE OF CARBON.
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