Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
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Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
It is evident that the presence of another acid in the solution
examined for hydrocyanic acid would render the detection of _cyanides_
impossible, but in all cases hydrocyanic acid can be separated without
arriving at a decision in regard to its original state of combination.
Nitric, hydrochloric, and several other acids would not be distilled at
the temperature of the water-bath; an examination for these by the
methods already described can therefore be instituted simultaneously
with the search for hydrocyanic acid.
DETECTION OF ALKALIES AND ALKALINE EARTHS.
The separation of these bodies in the caustic state is a matter of
difficulty owing to the great tendency they possess to become converted
into carbonates; the carbonates of lime, baryta and strontia, moreover,
being non-poisonous in their effects, will not be employed with criminal
intent, and the carbonates of soda and potassa are extensively used as
pharmaceutical preparations. Notwithstanding the small chances of
success, the isolation of the compounds under consideration in the
caustic state is to be attempted.
To this intent, the organs to be analysed, together with their
contents, are placed in a glass retort provided with a receiver, water
added, and the mixture boiled. The distillate will contain the ammonia
present. When, however, putrefaction has begun, the detection of this
compound does not necessarily indicate its original presence in the
suspected materials. If, after an hour's boiling, the fluid in the
retort possess an alkaline reaction, it is to be examined for soda,
potassa, strontia, baryta and lime. The undistilled solution is
filtered, the filtrate evaporated to dryness, and the residual mass
treated with alcohol. By this treatment, potassa and soda go in
solution, lime, baryta and strontia[I]--as well as the alkaline
carbonates--remaining undissolved. The potassa and soda are separated
from the other salts present by filtering and evaporating the alcoholic
solution to dryness and then calcining the residue in a silver crucible.
The mass, which should still be alkaline, is then dissolved in dilute
sulphuric acid. If the solution is turbid, traces of baryta or strontia
may still be present and should be removed by filtration. Some
hydrochloric acid and solution of bichloride of platinum are then added
to a portion of the filtered liquid: in presence of _potassa_ a yellow
precipitate is formed.
[I] Baryta and strontia dissolve in alcohol, but only when they are
anhydrous and the alcohol is absolute, which is not the case here.
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