Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
Another portion is treated with tartaric acid: a white granular
precipitate is produced. Hydrofluosilicic acid is added to a third
portion of the solution: the formation of a gelatinous precipitate is a
further indication of the presence of potassa. If the preceding tests
have given negative results, and a white precipitate is formed by the
addition of antimonate of potassa to another portion of the solution,
_soda_ is present. In both cases, it is necessary to confirm the results
by means of the spectroscope.
The above reactions are distinctive only in the absence of metals
precipitated by sulphuretted hydrogen, sulphide of ammonium or carbonate
of soda, and small portions of the solution should be tested with these
reagents.
In order to detect baryta, strontia and lime, the residue, insoluble in
alcohol is dissolved in dilute nitric acid, and an excess of carbonate
of ammonia added to the solution: the three bases, if present, are
precipitated as carbonates. The precipitate formed is separated from the
solution by filtration, dissolved on the filter in dilute hydrochloric
acid, and the solution then filtered and divided into two parts:
sulphuric acid is added to one, the fluid filtered from the precipitate
of sulphate of baryta formed, and the filtrate treated with ammonia and
oxalate of ammonia. If _lime_ be present,--although its sulphate is not
easily soluble--sufficient will be contained in the filtrate to give a
white precipitate of oxalate of lime.
The remaining portion of the solution is evaporated to dryness, and the
residue treated with absolute alcohol. Chloride of strontium goes into
solution, chloride of barium remaining undissolved. If upon evaporating
the alcoholic solution a residue is obtained which, when dissolved in
water, produces turbidity in a solution of sulphate of lime, _strontia_
is present.
The residue, insoluble in alcohol, is dissolved in water. If a
precipitate is produced by the addition of sulphuric acid or
hydrofluosilicic acid to the solution, _baryta_ is present. The latter
reaction distinguishes baryta from strontia, which is not precipitated
by hydrofluosilicic acid. Should the tests mentioned above fail to give
affirmative results, and poisoning by means of baryta and strontia be
nevertheless suspected, these compounds may possibly have remained in
the materials contained in the alimentary canal, in the state of
insoluble sulphates. To effect their detection under these circumstances
the organic substances must be decomposed by means of sulphuric acid.
The carbonaceous residue is calcined in a crucible at an elevated
temperature, and the remaining mass treated with water. In this way, a
solution of sulphides of barium and strontium is obtained, which is then
tested as directed above.
DETECTION OF CHLORINE, BROMINE, AND IODINE.
CHLORINE AND BLEACHING CHLORIDES.
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