Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
1º. The paper is carefully examined in all of its parts, and in various
positions, by aid of a lens. In this way, either thinned points, caused
by erasure, or remaining traces of words, may possibly be discovered.
2º. The paper is next placed upon a perfectly clean piece of glass, and
completely and uniformly moistened with water. The glass is then
removed, and the transparency of the paper examined by aid of a lens.
When uniform transparency is exhibited, and certain portions are neither
more transparent nor more opaque than the rest of the paper, it is
probable that erasure has not been attempted. If, on the other hand,
opaque points are observed, it is almost certain that letters have been
erased, and sandarac, which is not affected by water, subsequently
applied. In case transparent points are detected, there is reason to
suspect that words have been removed, and the spots either left intact
or afterwards coated with a substance soluble in water, such as alum.
3º. The paper is dried and the above operation repeated with alcohol of
87 per cent. Indications may now be observed which failed to occur in
the treatment with water; as well as these latter confirmed. As alcohol
dissolves sandarac, the points that formerly appeared opaque may now
become transparent.
4º. The paper is again dried, then placed under a sheet of very thin
silk-paper, and a warm iron passed over it. This operation frequently
causes the reappearance of words that have been partially obliterated.
It is also advisable--as suggested by _M. Lassaigne_--to expose the
paper to the action of iodine vapors. If alteration has not been
attempted, the paper will acquire an uniform color; yellow, if sized
with gelatine; violet blue, if sized with the mixture of soap, resin and
starch. When, on the contrary, a subsequent sizing of gelatine has been
applied in order to mask the alteration--the paper having been
originally sized with the above mixture--it will assume in some portions
a yellow, in others a violet-blue color.
5º. It is ascertained whether the paper possesses an acid reaction. If
so, its acidity may result from the presence of hydrochloric acid, in
case the paper was washed with chlorine, or of other acids. Alum, used
to disguise erasure, would also cause an acid reaction. The mere
detection of acidity is, in itself, of little importance, as, in the
manufacture of paper, the pulp is bleached by means of chlorine, and
this reagent may not have been entirely removed by washing. If, however,
the paper is acid only in certain spots, and these points produce a red
coloration upon blue litmus paper, having the form of letters, the
indication is of value. In order to ascertain if this be the case, it is
advisable, before wetting the paper, to slightly press it upon a sheet
of moist litmus paper: the acid spots will then leave a reddish trace
upon the latter.
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