Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
6º. The manuscript under examination is again spread upon a glass-plate,
and a solution of tannin (or preferably, a solution of ferrocyanide of
potassium containing one per cent. of the salt, and acidulated with
acetic acid) applied by means of a brush. If the original writing was
executed with ordinary ink (which has as its base tannate of iron), and
the washing has been but imperfectly performed, it is quite possible
that a blue coloration will be produced by the action of the
ferrocyanide. It is, however, often necessary to apply the above
reagents several times before the original writing becomes apparent;
indeed, in some cases months have elapsed before the reaction has
occurred.
In case the alteration or destruction of the document is feared in the
above test, it is well to previously provide the court with a certified
copy, and then proceed with the examination.
7º. If the paper possesses a friable appearance, it has possibly been
washed with sulphuric acid. This property may however originate from
other causes, and the presence of the acid should be confirmed by
washing the document with distilled water, and adding a solution of
chloride of barium to the washings. The precipitate should form in a
considerable quantity, as a slight cloudiness could be due to sulphates
contained in the water used in the preparation of the pulp.
If much sulphuric acid be present, it may be so concentrated by heating
as to cause the carbonization of the paper.
8º. It is also well, should washing with sulphuric acid be suspected, to
ascertain, by aid of a lens, if the filaments on the surface of the
manuscript possess an inflated appearance. This would be caused by the
escape of carbonic acid, originating from the action of sulphuric acid
upon the carbonates contained in the water used in the manufacture of
the paper.
9º. Old ink is more difficult to remove than new, and it is therefore
sometimes possible to cause the reappearance of old writings, over which
words have been subsequently written. For this purpose, a solution
containing 50 per cent. of oxalic acid is applied with a fine brush over
the suspected points. As soon as the ink disappears, the acid is
immediately removed by washing with water, and the paper dried. Upon now
repeating the operation, the presence of a former writing may be
detected after the complete disappearance of the words last written.
10º. According to _M. Lassaigne_, when the same ink has not been used
throughout a document, washing with dilute hydrochloric acid will
demonstrate the fact. This acid, while causing the gradual obliteration
of characters written with ordinary ink--the shade of the paper not
being altered--produces a red color, if ink containing log-wood has been
employed, and a green coloration, in case the ink used contained
Prussian blue.
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