Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
The expert may possibly be called upon to give evidence as to the
existence of a "_trompe-l'oeil_;" as was the case in the trial of _M. de
Preigne_, which took place at Montpelier in 1852. A "_trompe-l'oeil_"
consists of two sheets of paper, glued together at the edges, but having
the upper sheet shorter than the other which therefore extends below it.
This species of fraud is executed by writing unimportant matter on the
uppermost sheet, and then obtaining the desired signature, care being
taken that it is written on the portion of the paper projecting below.
The signature having been procured, it is only necessary to detach the
two sheets in order to obtain a blank paper containing the signature,
over which whatever is desired can be inserted. The trial referred to
above, was in reference to a receipt for 3,000 francs. The expert, upon
placing pieces of moistened paper upon the suspected document, noticed
that they adhered to certain points, and that these formed a border
around the paper but passing _above_ the signature. The fraudulency of
the act was thus established, and so recognized by the court, although
the accused was acquitted by the jury.
Numerous means have been proposed, in order to render the falsification
of documents a matter of difficulty. The most reliable of these is the
use of "Grimpe's safety-paper," containing microscopic figures, the
reproduction of which is impossible. Unfortunately, up to the present,
the government has adopted methods less sure.
EXAMINATION OF WRITINGS IN CASES WHERE A SYMPATHETIC INK HAS BEEN
USED.
Sympathetic inks are those which, although invisible at the time of
writing, become apparent by the application of certain agents. They are
of two classes: those which are rendered visible by the mere application
of heat, such as chloride of cobalt, or the juice of onions; and those
which are brought out only by the action of a reagent. The inks of the
second class most frequently used are solutions of acetates of lead, and
other metals which give a colored sulphide when treated with
sulphuretted hydrogen. Characters written with a solution of
ferrocyanide of potassium acquire a blue color, if washed with a
solution of perchloride of iron. It is scarcely necessary to add that
the latter solution can be used as the ink, and the ferrocyanide as the
developer.
When the presence of characters written with a sympathetic ink is
suspected, the document is examined as follows:
1. The paper is at first warmed: if the ink used is of the first class,
the characters will now become legible; otherwise the examination is
continued as below.
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