Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence — John Shaqi
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
The above process possesses the undeniable advantage of completely
destroying the organic substances, at the same time avoiding the
introduction of sulphate of potassa, the presence of which impairs the
usefulness of the preceding method; but it necessitates the presence of
numerous foreign bodies in the substance to be analysed, and this should
be avoided. The _absolute purity_ of reagents is not always to be
attained, and the results of an analysis are the more certain, in
proportion as they are less numerous and more easily purified.
BY MEANS OF POTASSA AND NITRIC ACID.
It has been proposed, instead of using nitrate of lime, to dissolve the
organic matter in potassa and then saturate the fluid with nitric acid.
This method is evidently more complicated than the simple treatment with
nitrate of potassa, and possesses, moreover, no advantages over the
latter process.
BY MEANS OF CHLORATE OF POTASSA.
The organic materials are treated with an equal weight of pure
hydrochloric acid, and water added, so as to form a clear pulp. This
being accomplished, two grammes of chlorate of potassa are added to the
mixture at intervals of about five minutes. The fluid is next filtered,
and the insoluble residue remaining on the filter washed until the
wash-water ceases to exhibit an acid reaction. The filtrate is then
evaporated, an aqueous solution of sulphurous acid added, until the odor
of this reagent remains distinctly perceptible, and the excess of the
acid removed by boiling the solution for about an hour. The fluid is now
adapted to further examination for arsenic, or other metallic poisons.
This method is one of the best in use, both chlorate of potassa and
hydrochloric acid being reagents easily procured in a state of great
purity; their use, however, is liable to the objection that they convert
silver and lead into insoluble chlorides.
BY MEANS OF CHLORINE.
_M. Jacquelain_ suggests, in the search for arsenic, the decomposition
of the organic matters by means of a current of chlorine, and recommends
the following process: The organic substances are bruised in a mortar
and then macerated with water. The fluid so obtained, in which the
organic matter is held suspended, is next placed in a flask into which a
current of chlorine is passed until all the organic matter is deposited
in colorless flakes on the bottom of the vessel. The flask is then well
closed and allowed to stand for 24 hours, when the odor of the gas
should still be perceptible. The fluid is now filtered, the filtrate
concentrated by heating in a vessel which permits of the preservation of
the volatile chloride of arsenic possibly present, and then examined for
poisons.
This process fails to possess the degree of generality desirable, and
presents the disadvantage of requiring considerable time for its
execution.
BY MEANS OF AQUA REGIA.
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