Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiencesDarling, Charles R. (Charles Robert)
Science
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences
Darling, Charles R. (Charles Robert)
Drops; Liquids; Surface tension
*Other Examples of Equi-Density.*—There are many other liquids which,
like orthotoluidine, may be heavier or lighter than water, according to
temperature, and I now wish to bring to your notice the remarkable
liquid _aniline_, which falls under this head. Aniline is an oily
liquid, which, unless specially purified, has a deep red colour. It
forms the basis of the beautiful and varied colouring materials known as
the aniline dyes, which we owe to the skill of the chemist. The
equi-density temperature of water and aniline is 147° F. or 64° C.; that
is, aniline will sink in water if both be colder than 147° F., and rise
to the surface if this temperature be exceeded. We may illustrate this
fact by a simple but striking experiment. Here are two tall beakers side
by side, and above them a cistern containing aniline (Fig. 8). The stem
of the cistern communicates with the two branches of a horizontal tube,
the termination of one branch being near the top of one of the beakers,
whilst the other branch is prolonged to the bottom of the second beaker,
and is curved upwards at the end. Both branches are provided with taps
to regulate the flow of liquid, and to commence with are full of
aniline. Cold water is poured into the beaker containing the shorter
branch until the end is submerged; and water nearly boiling is placed in
the second beaker to an equal height. I now open the taps, so that the
aniline may flow gradually into each beaker; and you notice that the
drops of aniline sink through the cold water and rise through the hot.
We have thus the same liquid descending and ascending simultaneously in
water, the only difference being that the water is cold on the one side
and hot on the other. Prolonging the delivery-tube to the bottom of the
beaker containing the hot water enables the rising drops to be observed
throughout the length of the column of water; and in addition enables
the cold aniline from the cistern to be warmed up on its way to the
outlet, so that by the time it escapes its temperature is practically
the same as that of the water. If this temperature exceed 147° F., the
drops will rise. We might, in this experiment, have used orthotoluidine
instead of aniline; or, indeed, any other liquid equal in density to
water at some temperature intermediate between those of the hot and cold
water—always provided that the liquid chosen did not mix with water.
Amongst such other liquids may be mentioned _anisol_; _butyl benzoate_;
and _aceto-acctic ether_; but none of these possess the fine colour of
aniline or its chemical relative orthotoluidine, and in addition are
more costly liquids. Besides these are a number of other liquids rarer
still, practically only known to the chemist, which behave in the same
way. These liquids are all carbon compounds, and more or less oily in
character. There is a simple rule which may be used to predict whether
any organic liquid will be both lighter and heavier than water,
according to temperature.
Public-domain text, read in full here on John Shaqi.
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