Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiencesDarling, Charles R. (Charles Robert)
Science
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences
Darling, Charles R. (Charles Robert)
Drops; Liquids; Surface tension
Here it is: If the density of the liquid at
32° F. or 0° C. be not greater than 1·12, the liquid will become less
dense than water below 212° F. or 100° C., at which temperature water
boils. This rule is derived from a knowledge of the extent to which the
expansion of organic liquids in general exceeds that of water. I have
considered it necessary to enter at some length into this subject of
equi-density, as much that will follow involves a knowledge of this
physical relation between liquids.
*Aniline Films or Skins.*—We have previously concluded, largely from
circumstantial evidence, that a liquid drop is encased in a skin or what
is equivalent to a skin, and I propose now to show by experiments with
aniline how we can construct a drop, commencing with a skin of liquid.
Here is some aniline in a vessel, covered by water. I lower into the
aniline a circular frame of wire, which I then raise slowly into the
overlying water; and you observe that a film of aniline remains
stretched across the frame. By lifting the frame up and down in the
water the skin is stretched, forming a drop which is constricted near
the frame (Fig. 9). On lifting the wire more suddenly, the skin of
aniline closes in completely at the narrow part, and a sphere of water,
encased in an aniline skin, then falls through the water in the beaker,
and comes to rest on the aniline below—into which, however, it soon
merges. You were previously asked to regard a drop of liquid as being
similar to a filled soap-bubble; and this experiment realizes the terms
of the definition. And it requires only a little imagination to picture
a drop surrounded by its own skin instead of that of another liquid. It
is easy to make one of these enclosed water-drops by imitating the
blowing of a soap-bubble—using, however, water instead of air. In order
to do this I take a piece of glass tubing, open at both ends, and pass
it down the vessel, until it reaches the aniline. Water, in the
meantime, has entered the tube, to the same height as that at which it
stands in the vessel. On raising the tube gently, a skin of aniline
adheres to the end; and as we raise it still further, the water in the
tube, sinking so as to remain at the level in the vessel, expands the
skin into a sphere (Fig. 9)—the equivalent of a filled soap-bubble. On
withdrawing the tube gradually, the composite sphere is left hanging
from the surface of the water.
[Illustration: __Fig._ 9.—Aniline skins enveloping water._]
Public-domain text, read in full here on John Shaqi.
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