Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences — John Shaqi
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiencesDarling, Charles R. (Charles Robert)
Science
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences
Darling, Charles R. (Charles Robert)
Drops; Liquids; Surface tension
to rest at the bottom of the beaker, becomes more and more rounded, and
finally spherical. Then, unaided, it rises to the top and mingles itself
with the aniline which remained on the surface. After a brief interval a
second drop falls, imitating the performance of the first one; and, like
its predecessor, rises to the surface, after remaining for a short time
at the bottom of the vessel. And so long as we keep the temperature a
few degrees above that of equi-density, the process of partition and
reunion goes on indefinitely. The action is automatic and continuous,
and the large size of the drop and of the neck, and the slowness of the
procedure, enables us to follow with ease every stage in the formation
of a parting drop.
[Illustration: __Fig._ 21._]
[Illustration: __Figs._ 21 and 22.—Automatically formed aniline drops,
showing the formation of droplets from the neck._]
And now as to the explanation of this curious performance. When the
aniline reaches the surface, and spreads out, it cools by contact with
the air more rapidly than the water below. As it cools, its density
increases, and soon becomes greater than that of the water, in which it
then attempts to sink. The forces of surface tension prevent the whole
of the aniline from falling—the water surface can sustain a certain
weight of the liquid—but the surplus weight cannot be held, and
therefore breaks away. But when the detached drop reaches the bottom of
the vessel, it is warmed up again; and when its temperature rises above
that of equi-density it floats up to the top. And so the cycle of
operations becomes continuous, owing to cooling taking place at the top
and heating at the bottom.
Perpetual motion, you might suggest. Nothing of the kind. Perpetual
motion means the continuous performance of work without any supply of
energy; it does not mean merely continuous movement. A steam-engine
works so long as it is provided with steam, and an electric motor so
long as it is fed with electricity; but both stop when the supply of
energy is withdrawn. So with our aniline drop, which derives its energy
from the heat of the water, and which comes to rest immediately the
temperature falls below 147° F. or 64° C. But in order that the process
of separation and reunion may continue, the cooling at the top is quite
as necessary as the heating at the bottom. Our aniline drop is in
essence a heat-engine—although it does no external work—and like all
heat-engines possesses a source from which heat is derived, and a sink
into which heat at a lower temperature is rejected. We might, with
certain stipulations, work out an indicator diagram for our liquid
engine, but that would be straying too far from our present subject.
Public-domain text, read in full here on John Shaqi.
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