Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences — John Shaqi
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiencesDarling, Charles R. (Charles Robert)
Science
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences
Darling, Charles R. (Charles Robert)
Drops; Liquids; Surface tension
*Automatic Drops of other Liquids.*—Liquids which possess a low
equi-density temperature with water do not form automatic drops like
aniline, as the rate of cooling at the surface is too slow, and hence
the floating mass of liquid does not attain a density in excess of that
of the water beneath. Aceto-acetic ether, however, behaves like aniline,
if the temperature of the water be maintained at about 170° F. (77° C.),
but as this liquid is fairly soluble in hot water further quantities
must be added during the progress of the experiment. Results equal to
those obtained with aniline, however, may be secured by using
nitrobenzene in nitric acid of specific gravity 1·2 at 59° F. (15° C.),
the acid being heated to 185° F. (85° C.); and here you see the yellow
drop performing its alternate ascents and descents exactly as in the
case of aniline and water. Other examples might be given; but we may
take it as a general rule that when the equi-density temperature of the
liquid and medium is above 125° F. (52° C.), the phenomenon of the
automatic drop may usually be observed when the temperature is raised by
30° F. (17° C.), above this point.
*Liquid Jets.*—So far we have been observing the formation of single
drops, growing slowly at the end of a tube, or breaking away from a
large mass of the floating liquid. If, however, we accelerate the speed
at which the liquid escapes, the drop has no time to form at the outlet,
and a jet is then formed. We are all familiar with a jet of water
escaping from a tap; it consists of an unbroken column of the liquid up
to a certain distance, depending upon the pressure, but the lower part
is broken up into a large number of drops, which break away from the
column at a definite distance from the tap. There are many remarkable
features about jets which I do not intend to discuss here, as it is only
intended to consider the manner in which the drops at the end are
formed. To observe this procedure, it is necessary again to resort to
our method of slowing down the rate of formation, by allowing the liquid
to flow into a medium only slightly inferior in density. For this
purpose, orthotoluidine falling into water at the ordinary room
temperature is eminently satisfactory; and we see on the screen the
projection of a pipe, with its end under water, placed so that a jet of
orthotoluidine may be discharged vertically downwards from a stoppered
funnel. I open the tap slightly at first, and we then merely form a
single drop at the end. Now it is opened more widely, and you observe
that the drop breaks away some distance below the outlet, being rapidly
succeeded by another and another (Fig. 23). On still further opening the
tap the drops form at a still greater distance from the end of the pipe,
and succeed each other more rapidly, so that quite a number appear in
view at any given moment (Figs. 24 and 25). Notice how the drop is
distorted by breaking away from the stream of liquid, and how it
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