Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiencesDarling, Charles R. (Charles Robert)
Science
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences
Darling, Charles R. (Charles Robert)
Drops; Liquids; Surface tension
pull, whereas B and C can only exert their strength at an angle, and the
larger the angle the more they are handicapped. If A be more powerful
than B and C, the globule will spread; but the result of the spreading
is to diminish the angles at which the pulls of B and C are inclined to
the surface, and hence their effective opposition to A will be
increased. Moreover, the spreading of the liquid diminishes the surface
tension of the water—that is, weakens A—and hence it becomes possible
for B and C to prevail and draw back the surface of the globule which A
had previously stretched. If, in spite of these disabilities, A should
still be the stronger, the globule will be stretched until it covers the
whole surface; whereas if B and C overcome A, the globule will shrink,
increasing the angles at which B and C operate, and therefore reducing
their effective pulls, until their combined strength is equal to that of
A, when the globule will remain at rest. Bearing these facts in mind, we
can understand why a small drop of oil placed on a clean water surface
spreads across; for in this case A is stronger than B and C combined.
But when the surface of the water is covered with a layer of oil, A is
weakened, and can no longer overcome the opposing pulls of B and C.
Hence a further drop of oil poured on to the surface remains in the form
of a globule.
*Movements due to Solubility.*—When small fragments of camphor are
placed on the surface of water some remarkable movements are seen.³ The
bits of camphor move about with great rapidity over the surface, and
generally, in addition, show a rapid rotary motion. The explanation
usually given is that the camphor dissolves in the water at the points
of contact forming a solution which possesses a less surface tension
than pure water. This solution is in consequence stretched by the
tension of the rest of the surface, and the camphor floating on its
solution is therefore made to move in the direction of the line along
which the stretching force happens to be the greatest. But the camphor
continues to dissolve wherever it goes, and is therefore continuously
pulled about as a result of this interplay of tensions. Touching the
surface with a wire which has been dipped in oil immediately arrests the
movements, owing to the tension of the water being diminished to such an
extent by the skin of oil that it is no longer competent to stretch the
part on which the camphor floats. No doubt this explanation is correct
so far as it goes, but it is highly probable that when the floating
substance dissolves, other forces are called into action in addition to
the tensions.
³ These movements were first recorded by Romieu in 1748 and were
ascribed by him to electricity.
[Illustration: __Fig._ 36.—Aniline globules on a water surface._]
Public-domain text, read in full here on John Shaqi.
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