Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences — John Shaqi
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiencesDarling, Charles R. (Charles Robert)
Science
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences
Darling, Charles R. (Charles Robert)
Drops; Liquids; Surface tension
*Spreading of Oil on the Surface of Water.*—If a small drop of oil be
placed on the surface of water it will be observed to spread immediately
until it forms a thin layer covering the surface. If a further addition
of the oil be made, globules will be formed, which, as you now see upon
the screen, remain floating on the surface. The spreading of the oil in
all directions from the place on which the small quantity of oil was
dropped is due to the superior surface tension of water, which pulls the
oil outwards. The surface tension of the oil opposes that of the water,
and would prevent the drop from spreading were it not overcome by a
greater force. The result is the same as would be observed if the centre
or any other part of a stretched rubber disc were weakened; the weak
part would be stretched in all directions, and the rest of the disc
would shrink towards the sides. When the oil has spread out, however,
and contaminated, as it were, the surface of the water, the surface
tension is reduced, and is not sufficiently strong to stretch out a
further quantity of oil, which, if added, remains in the form of a
floating globule.
[Illustration: __Fig._ 35.—Forces acting on a floating globule._]
Let us study the forces at work on the floating globule a little more
closely. Its upper surface is in contact with air, and the surface
tension tends, as usual, to reduce the area to a minimum. The top of the
globule is not flat, but curved (Fig. 35), and its surface meets that of
the water at an angle; and the counter-pull exerted against the
stretching-pull of the water surface is not horizontal, but inclined in
the direction of the angle of contact, as shown by the line B. The under
part of the globule is also curved, and meets the water surface from
below at an angle; and here also is exerted a pull in opposition to that
of the water surface, different in magnitude to the force at the upper
surface, but also directed at the angle of contact as shown by the line
C. This tension at the joining surface of two liquids is called the
“interfacial” tension, to distinguish it from that of a surface in
contact with air. Acting against these two tensions is that of the
water, which is directed horizontally along the surface, as shown by the
line A. The lines A, B, and C indicate the forces acting at a single
point; but the same forces are at work at every point round the circle
of contact of the globule and the surface of the water. And therefore
the tendency on the part of the water tension is to cause the globule to
spread out in all directions, whereas the other two tensions tend to
prevent any enlargement of its surface. The result depends upon the
magnitudes and directions of the conflicting forces. We can imagine a
kind of tug-of-war taking place, in which one contestant, A, is opposed
to two others, B and C, all pulling in the directions indicated in Fig.
35. Although A is single-handed, he has the advantage of a straight
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