Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
This paper, though subsequent to that of Clausius, is very different in
character. Many of the results are identical with those previously
obtained by Clausius, but they are reached by a process which is
preceded by a clear statement of fundamental principles. These
principles have since been the subject of discussion, and are not free
from difficulty even now; but a great step in advance was made by their
careful formulation in Thomson's paper, as a preliminary to the
erection of the theory and the deduction of its consequences. Two
propositions are stated which may be taken as the First and Second Laws
of Thermodynamics. One is equivalent to the First Law as stated in p.
116, the other enunciates the principle of Reversibility as a criterion
of "perfection" of a heat engine. We quote these propositions.
"Prop. I (Joule).--When equal quantities of mechanical effect are
produced by any means whatever from purely thermal sources, or lost in
purely thermal effects, equal quantities of heat are put out of
existence or are generated."
"Prop. II (Carnot and Clausius).--If an engine be such that when worked
backwards, the physical and mechanical agencies in every part of its
motions are all reversed, it produces as much mechanical effect as can
be produced by any thermodynamic engine, with the same temperatures of
source and refrigerator, from a given quantity of heat."
Prop. I was proved by assuming that heat is a form of energy and
considering always the work effected by causing a working substance to
pass through a closed cycle of changes, so that there was no change of
internal energy to be reckoned with.
Prop. II was proved by the following "axiom": "It is impossible, by
means of inanimate material agency, to derive mechanical effect from any
portion of matter by cooling it below the temperature of the coldest of
the surrounding objects." This is rather a postulate than an axiom; for
it can hardly be contended that it commands assent as soon as it is
stated, even from a mind which is conversant with thermal phenomena. It
sets forth clearly, however, and with sufficient guardedness of
statement, a principle which, when the process by which work is done is
always a cyclical one, is not found contradicted by experience, and one,
moreover, which can be at once explicitly applied to demonstrate that no
engine can be more efficient than a reversible one, and that therefore
the efficiency of a reversible engine is independent of the nature of
the working substance.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account