Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
It has been suggested by Clerk Maxwell that this "axiom" is contradicted
by the behaviour of a gas. According to the kinetic theory of gases an
elevation of temperature consists in an increase of the kinetic energy
of the translatory motion of the gaseous particles; and no doubt there
actually is, from time to time, a passage of some more quickly moving
particles from a portion of a gas in which the average kinetic energy is
low, to a region in which the average kinetic energy is high, and thus a
transference of heat from a region of low temperature to one of higher
temperature. Maxwell imagined a space filled with gas to be divided into
two compartments A and B by a partition in which were small massless
trapdoors, to open and shut which required no expenditure of energy. At
each of these doors was stationed a "sorting demon," whose duty it was
to allow every particle having a velocity greater than the average to
pass through from A to B, and to stop all those of smaller velocity than
the average. Similarly, the demons were to prevent all quickly moving
particles from going across from B to A, and to pass all slowly moving
particles. In this way, without the expenditure of work, all the quickly
moving particles could be assembled in one compartment, and all the
slowly moving particles in the other; and thus a difference of
temperatures between the two compartments could be brought about, or a
previously existing one increased by transference of heat from a colder
to a hotter mass of gas.
Contrary to a not uncommon belief, this process does not invalidate
Thomson's axiom as he intended it to be understood. For the gas referred
to here is what he would have regarded as the working substance of the
engine, by the cycles of which all the mechanical effect was derived;
and it is not, at the end of the process, in the state as regards
average kinetic energy of the particles in which it was at first. That
this was his answer to the implied criticism of his axiom contained in
Maxwell's illustration, those who have heard him refer to the matter in
his lectures are well aware. But of course it is to be understood that
the substance returns to the same state only in a statistical sense.
Public-domain text, read in full here on John Shaqi.
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