Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
In this reckoning the definition of any temperature, let us say 37° C.,
is the temperature of the vessel and its contents when the top of the
mercury column stands at the mark 37 above 0, on the scale defined by
the graduation of the instrument; but the numerical signification with
relation to the volumes is given by equation (D). This shows that the
numerical measure of any temperature involves both the expansion of the
vessel and that of the glass vessel between the temperature of melting
ice and the temperature in question. This result may be contrasted with
the erroneous statement frequently made that equal increments of
temperature correspond to equal increments of the volume of the
thermometric substance. It also shows that different mercury-in-glass
thermometers, however accurately made and graduated, need not agree when
placed in a bath at any other temperature than 0° C. or 100° C. This
fact, and the results of the comparison of thermometers made with
different kinds of glass with the normal air thermometer, which was
carried out by Regnault, were always insisted on by Thomson in his
teaching when he dealt with the subject of heat. The scale of a
mercury-in-glass thermometer is too often in text-books, and even in
Acts of Parliament regarded as a perfectly definite thing, and the
expansion of a gas is not infrequently defined by this indefinite scale,
instead of being used as it ought to be, as the basis of definition of
the scale of the gas thermometer. The whole treatment of the so-called
gaseous laws is too often, from a logical point of view, a mass of
confusion.
In his article on Heat Thomson gave two definitions of the scale of
absolute temperature. One is that stated on p. 126 above, namely, that
the temperature of the source and refrigerator are in the ratio of the
heat taken in from the source to the heat given to the refrigerator,
when the engine describes a Carnot cycle consisting of two isothermal
and two adiabatic changes.
The other definition is better adapted for general use, as it applies to
any cycle whatever which is reversible. Let the working substance
expand under constant pressure by an amount dv (AB' in Fig. 12), and let
heat H be given to the substance at the same time. The external work
done is pdv. Thomson called pdv⧸H the work ratio. Now let the
temperature be raised by dT without giving heat to the substance or
taking heat from it, and let the corresponding pressure rise be dp; and
call dp⧸p the pressure ratio. The temperature ratio dT⧸T is equal to
the product of the work ratio and the pressure ratio, that is,
dT⧸T = dvdp⧸H
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account