Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
This is clearly true; for dvdp is the area of a cycle like AB'C'D,
represented in Fig. 12, for which an amount of heat H is taken in,
though not in this case strictly at one temperature. And clearly, since
in Fig. 12 the change from B' to B is adiabatic, H is the heat which
would have to be taken in for the isothermal change AB in the Carnot
cycle ABCD, which has the same area as AB'C'D. Thus the efficiency of
the cycle is dvdp⧸H, and this by the former definition is dT⧸T.
Or we may regard the matter thus:--The amount of heat H which
corresponds to an infinitesimal expansion dv may be used in equation (A)
whether the expansion is isothermal or not, if we take T as the average
temperature of the expansion. Hence we have dp⧸dT = H⧸(dv.T), that is,
dT⧸T = dpdv⧸H. The theorem on p. 128 is obtained by what is virtually
this process.
COMPARISON OF ABSOLUTE SCALE WITH SCALE OF AIR THERMOMETER
The comparison which Joule and Thomson carried out of the absolute
thermodynamic scale with the scale of the constant pressure gas
thermometer has already been referred to, and it has been shown that the
two scales would exactly agree, that is, absolute temperature would be
simply proportional to the volume of the gas in a gas thermometer kept
at the temperature to be measured, if the internal energy of the gas
were not altered by an alteration of volume without alteration of
temperature, that is, if the de - ∂e of p. 107 above were zero. Joule
tested whether this was the case by immersing two vessels, connected by
a tube which could be opened or closed by a stopcock, in the water of a
calorimeter, ascertaining the temperature with a very sensitive
thermometer, and then allowing air which had already been compressed
into one of the vessels to flow into the other, which was initially
empty. It was found that no alteration of temperature of the water of
the calorimeter that could be observed was produced. But the volume of
the air had been doubled by the process, and if any sensible alteration
of internal energy had taken place it would have shown itself by an
elevation or a lowering of the temperature of the water, according as
the energy had been diminished or increased.
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