Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
Thomson suggested that the gas to be examined should be forced through a
pipe ending in a fine nozzle, or, preferably, through a plug of porous
material placed in a pipe along which the gas was forced by a pump, and
observations made of the temperature in the steady stream on both sides
of the plug. The experiments were carried out with a plug of compressed
cotton-wool held between two metal disks pierced with holes, in a tube
of boxwood surrounded also by cotton-wool, and placed in a bath of water
closely surrounding the supply pipe. This was of metal, and formed the
end of a long spiral all immersed in the bath. Thus the temperature of
the gas approaching the plug was kept at a uniform temperature
determined by a delicate thermometer; another thermometer gave the
temperature in the steady stream beyond the plug.
In the case of hydrogen the experiments showed a slight heating effect
of passage through the plug; air, oxygen, nitrogen and carbonic acid
were cooled by the passage.
The theory of the matter is set forth in the original papers, and in a
very elegant manner in the article on Heat. The result of the analysis
shows that if ∂w be the positive or negative work-value of the heat
which will convert one gramme of the gas after passage to its original
temperature; and T be absolute temperature, and v volume of a gramme of
the gas at pressure p, and the difference of pressure on the two sides
of the plug be dp, the equation which holds is
(1⧸T) (∂T⧸∂v) = 1⧸{v + (∂w⧸dp)} ... (E)[18]
It was found by Joule and Thomson that ∂w was proportional to dp for
values of dp up to five or six atmospheres. At different temperatures,
however, in the case of hydrogen the heating effect was found to
diminish with rise of temperature, being .100 of a degree centigrade at
4° or 5° centigrade, and .155 at temperatures of from 89° to 93°
centigrade for a difference of pressure due to 100 inches of mercury.
If there is neither heating nor cooling ∂w = 0, and we obtain by
integration T = Cv, where C is a constant.
Elaborate discussions of the theory of this experiment will be found in
modern treatises on thermodynamics, and in various recent memoirs, and
the differential equation has been modified in various ways, and
integrated on various suppositions, which it would be out of place to
discuss here.
Public-domain text, read in full here on John Shaqi.
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