Louis Pasteur: His Life and LaboursVallery-Radot, René
Science
Louis Pasteur: His Life and Labours
Vallery-Radot, René
Pasteur, Louis, 1822-1895; Scientists -- France -- Biography
The first care of Pasteur, after having discovered the left-handed
tartaric acid and the constitution of paratartaric acid, was to compare
very carefully the properties of the new left-handed acid with those of
the right, endeavouring to determine by strict experiment the influence
on these properties of the internal atomic arrangements of the two
acids. Although we are unable to picture the exact figure of these
atomic groupings, there can be no doubt that they are formed of the
same elementary particles, that they are, moreover, dissymmetrical, and
that, in short, the dissymmetry of the one group is the same as that of
the other, but in an inverse sense. If, for example, the arrangement
of the atoms of the right-handed tartaric acid present the exterior
appearance of an irregular pyramid, the arrangement of the atoms of the
left-handed tartaric acid ought, of necessity, to present the form of a
pyramid irregular in the inverse sense.
II.
Nominated assistant professor of chemistry at Strasburg, Pasteur
followed up with enthusiasm these curious studies. To interrupt them
for an instant it required nothing less than his engagement with
Mademoiselle Marie Laurent, daughter of the Rector of the Academy.
It is even asserted that on the very morning of his marriage it was
necessary to go to his laboratory and remind him of the event that
was to take place on that day. But if Pasteur was thus guilty of an
absent-mindedness worthy of La Fontaine, he proved as a husband so
different from La Fontaine that Madame Pasteur, when reminded of this
lapse of memory, receives the reminder with an indulgent smile.
But to return to the laboratory: Under the same conditions of weight,
temperature, and quantity of solvent, Pasteur placed successively, in
presence of the two acids, all the substances capable of combining with
them. In this way he obtained right-handed and left-handed tartrates
of potash, of soda, of ammonia, of lime, and of all the oxides
properly so called. He applied himself to the compounds--and they are
numerous--which deposit themselves in liquids under well-determined
crystalline forms. Without entering into the details of these long
and patient studies, it may be stated generally that Pasteur proved
that whatever could be done with one of the tartaric acids could be
repeated rigorously, under similar conditions, with the other, the
resultant products manifesting constantly the same properties, with
the single difference already exhibited by the two acids--that in the
one case the deviation of the plane of polarisation was to the right,
while in the other it was to the left. With regard to all their other
properties, both chemical and physical, the identity was absolute.
Solubility, simple refraction by solutions, double refraction by
crystals, the action of heat in producing decomposition, &c., the
similitude extended to the most perfect identity.
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