Marvels of Scientific Invention: An Interesting Account in Non-Technical Language of the Invention of Guns, Torpedoes, Submarine Mines, Up-to-Date Smelting, Freezing, Colour Photography, and Many Other Recent Discoveries of ScienceCorbin, Thomas W.
Science
Marvels of Scientific Invention: An Interesting Account in Non-Technical Language of the Invention of Guns, Torpedoes, Submarine Mines, Up-to-Date Smelting, Freezing, Colour Photography, and Many Other Recent Discoveries of Science
Corbin, Thomas W.
Inventions
Let us imagine a vessel filled with water to which has been added a
little sulphuric acid, while suspended in it are two strips of platinum.
There is a space between the strips, so that when their upper ends are
suitably connected to a source of electric current that current flows
from one strip to the other _through the liquid_.
That is an example of the apparatus for carrying out this electrical
separation in its simplest form, and it will facilitate the further
description if the names of various parts are enumerated.
The process itself is electrolysis; the liquid is the electrolyte, while
the strips are the electrodes. The individual electrodes, again, have
special names, that by which the current enters being the anode and that
by which it leaves the cathode. It is not difficult to remember which is
which if we bear in mind that the current traverses them in alphabetical
order. Since, however, it may not be easy for the general reader to
carry all these terms in his mind, we will, when it is necessary to
differentiate between the two electrodes, call one the in-electrode and
the other the out-electrode.
Returning now to our imaginary apparatus, let us turn on the current. At
first nothing seems to be happening, although suitable instruments would
show that current was flowing. Soon, however, little bubbles appear upon
the electrodes, and these grow larger and larger, until they detach
themselves from the platinum to which they have been adhering, float up
to the surface and burst. The question which naturally arises is, What
do those bubbles consist of? Are they air?
If we take means to collect the gases which formed them we get an
unmistakable answer. The bubbles which arise from the in-electrode are
oxygen, those from the other hydrogen. If we allow our apparatus to work
for some time, and collect all the gas which arises, we shall find that
there is twice as much hydrogen as oxygen. We shall also find, as the
process goes on, that the quantity of water diminishes.
Perhaps I may be allowed at this point to remind my readers that water
is a collection of minute ultra-microscopic particles called
"molecules," each of which is formed of three smaller particles still
called "atoms." Of the three atoms two are hydrogen and one oxygen.
Water therefore consists of hydrogen and oxygen, there being twice as
much of the former as there is of the latter.
We see, therefore, that electrolysis gives us hydrogen and oxygen in
exactly those proportions in which they occur in water, and since we
also see that as these gases appear the water itself disappears, we are
led to conclude that the current is splitting up the water into the
gases of which it is formed.
But the strange thing is that this will not work with pure water. We
have to add something to it. In the case of our imaginary experiment it
was sulphuric acid. What part does that play?
Public-domain text, read in full here on John Shaqi.
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