Marvels of Scientific Invention: An Interesting Account in Non-Technical Language of the Invention of Guns, Torpedoes, Submarine Mines, Up-to-Date Smelting, Freezing, Colour Photography, and Many Other Recent Discoveries of ScienceCorbin, Thomas W.
Science
Marvels of Scientific Invention: An Interesting Account in Non-Technical Language of the Invention of Guns, Torpedoes, Submarine Mines, Up-to-Date Smelting, Freezing, Colour Photography, and Many Other Recent Discoveries of Science
Corbin, Thomas W.
Inventions
This is not fully understood, but we may be able to form a mental
picture of what is believed to happen as follows.
The in-electrode is surrounded by a vast assemblage of these tiny
molecules, most of them those of water, but a few those of the acid. The
latter are more complex in their structure than the former, but they too
contain hydrogen. Current flows into the electrode and instantly
hydrogen atoms from the _acid_ molecules crowd round it, like boatmen at
the seaside anxious to secure a passenger. Each takes on board a
quantity of electricity and with it darts across the intervening space
to the other electrode. Arrived there, it gives up its load and, its
work done, remains lying upon the electrode until enough others like
unto itself have gathered there to form a bubble and so escape. These
hydrogen atoms are thought to be the _craft which carry the current
through the liquid_ and enable it to pose, as it were, as a conductor of
electricity, which in reality it is not.
But where does the oxygen come from?
To find the answer to that we must add a second chapter to our story.
When the hydrogen "boats" took on board their load of electricity they
left their former associates, and these forthwith "set upon"
neighbouring water molecules and with the audacity of highwaymen stole
from them enough hydrogen atoms to take the place of those they had
lost. Thus the acid molecules became complete once more, while the scene
of the conflict near the in-electrode was strewn with the remains of the
water molecules from which the hydrogen atoms had been stolen. These
remains, of course, would be oxygen, and they, collecting together on
the electrode, would eventually be in numbers sufficient to form bubbles
and so escape.
Thus it may be the acid which really does the work, yet because of its
subsequent raid upon the water it is the latter which disappears, and it
is the materials of the latter which are bought to the surface in the
bubbles.
And there we see the mechanism whereby, so it is believed, electric
current can pass through otherwise non-conducting liquids. And the
important point, as far as practical utility is concerned, is that the
passage of the current is accompanied by a splitting up of something or
other, either the water or something in it, the materials of which are
deposited, one on one electrode and the other on the other.
And now we can proceed to those useful applications of electrolysis, the
commonest of which, perhaps, is electro-plating.
We have seen how electrolysis causes hydrogen, probably out of the acid,
to be deposited upon one electrode. Suppose that, instead of an acid, we
put in the water one of those substances known to chemists as a "salt,"
the commonest example of which is ordinary table salt. This well-known
condiment is caused by the interaction of hydrochloric acid and the
metal sodium and will serve to illustrate what all salts are.
Public-domain text, read in full here on John Shaqi.
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