Marvels of Scientific Invention: An Interesting Account in Non-Technical Language of the Invention of Guns, Torpedoes, Submarine Mines, Up-to-Date Smelting, Freezing, Colour Photography, and Many Other Recent Discoveries of ScienceCorbin, Thomas W.
Science
Marvels of Scientific Invention: An Interesting Account in Non-Technical Language of the Invention of Guns, Torpedoes, Submarine Mines, Up-to-Date Smelting, Freezing, Colour Photography, and Many Other Recent Discoveries of Science
Corbin, Thomas W.
Inventions
We have seen how the passage of current through acidulated water
produces hydrogen and oxygen. If those gases be collected in closed
vessels over the water, so that they remain in contact with the water,
as soon as the current is stopped a reverse action sets in. The gases
tend to recombine with the electrolyte and in so doing to give back a
current equal to that which formed them. Fig. 4 shows the construction
of what is called a voltameter, in which the gases arising from the
electrodes are collected in little glass vessels placed just above them.
Such an apparatus enables us to see easily how the accumulator works.
The picture shows the battery which is effecting the separation of the
oxygen and hydrogen. If that be disconnected, and the wires joined, as
shown by the dotted line, a current will flow back until the oxygen and
hydrogen have returned into the solution again. The apparatus will, in
fact, work like an ordinary battery, except that instead of a plate or
rod of zinc a mass of hydrogen will form the essential part.
An appliance such as a voltameter is not of much use for the practical
purpose of storing large quantities of electrical energy, because the
surfaces of the electrodes are so small and the surfaces where liquid
and gases are in contact are small too. It is clear that the larger the
electrodes are the wider will be the passage for the current, just as a
wide road can accommodate more traffic than a narrow path. We may regard
the electrodes as like gateways through which the current passes. By
making them large, therefore, we enable a large current to pass, and
consequently permit electrolysis to take place with great comparative
rapidity.
[Illustration: FIG. 4.]
The "plates," as the electrodes in a secondary battery are termed, are
generally large metal plates. Experiment has shown that lead is the best
for this purpose. It has also been found that it can be improved by
making it porous, since the inner surfaces of the pores are so much
added surface through which current can pass into the electrolyte. There
are various ways of producing this porosity, which need not trouble us
here, however. It will suffice for our purpose to understand that an
ordinary secondary cell consists of two lead plates, with the largest
possible surface, immersed in a liquid, generally a dilute solution of
sulphuric acid in water.
Public-domain text, read in full here on John Shaqi.
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