Medical Jurisprudence, Volume 2 (of 3)Paris, John Ayrton
Science
Medical Jurisprudence, Volume 2 (of 3)
Paris, John Ayrton
Medical laws and legislation -- Great Britain
It has lately been discovered that vegetable _gluten_, as existing in
wheat flour, is capable of producing upon corrosive sublimate the same
chemical decomposition, as that which we have stated to arise from the
action of albumen; whence the administration of wheat flour and water
has been suggested as a ready antidote. On the trial of _Michael
Whiting_, for administering poison (_corrosive sublimate_) to his
brothers-in-law, _George_ and _Joseph Langman_, the housekeeper,
_Catharine Carter_, stated in evidence, that the flour, (which was
subsequently proved to contain corrosive sublimate) could scarcely be
made into dumplings with milk[281]; and another witness, _Mrs. Hopkins_,
a neighbour who took charge of the dumpling that had not been boiled,
described it as “_a comical sort of paste; like glazier’s putty more
than paste, though not greasy_.” In order to ascertain the correctness
of this statement, we mixed powdered sublimate with wheat flour, and
proceeded to make it into dough with milk; when the same difficulty as
that stated by the above witnesses, embarrassed the process, and
satisfied us of the truth of their testimony. The phenomenon would
appear to depend upon the mutual chemical changes which arise in the
gluten and mercurial salt.
_Organic Lesions discovered on Dissection._
The œsophagus and stomach will be found inflamed, and sometimes eroded,
as in poisoning by arsenic. _Salin_ has asserted, that this salt never
produces perforation of the intestinal tube; this, however, is not the
fact; and we know not of any exclusive appearances, by which the organic
lesions inflicted by this poison can be distinguished, unless indeed it
be the black appearance of the stomach, as if it had been burnt, which
occasionally presents itself.
_Of the Chemical Processes by which the presence of Corrosive Sublimate
may be detected._
As the chemist, devoted to forensic enquiry, will be required to
identify this substance under very different states of mixture and
combination, we shall proceed to enumerate the various obstacles that
may possibly oppose his researches; and, at the same time, to suggest
the expedients by which they may be successfully evaded. Unlike
arsenious acid, corrosive sublimate is so readily decomposed by various
alimentary substances, that, when we attempt to demonstrate its presence
in such mixtures, we shall be more frequently compelled to rest our
proof upon the products of the analysis, than upon the actual
reproduction of the salt.
We shall proceed to consider the best modes of establishing the presence
of this salt, in the different forms in which it may occur, viz. 1, _In
the solid form_; 2, _Dissolved in water or spirit_; 3, _In various
coloured liquids_; 4, _In a state of mixture with various solids_; 5,
_Combined with solid or liquid aliments, by which it undergoes
decomposition_; 6, _In a state of combination with the textures of the
alimentary canal_.
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