Medical Jurisprudence, Volume 2 (of 3)Paris, John Ayrton
Science
Medical Jurisprudence, Volume 2 (of 3)
Paris, John Ayrton
Medical laws and legislation -- Great Britain
1. _The sublimate is in its solid form._ The external characters by
which this salt is distinguished will go far to establish its identity;
but the fact should always receive the support of a chemical proof; and
as this is to be derived from the phenomena afforded by its solutions
through the intervention of various tests, it will meet with full
consideration in the following section, viz.
2. _The salt is in the state of solution, in water, or spirit._ Let us
then suppose that we have a solution of some body in distilled water,
which we suspect to be corrosive sublimate, by what means are we able to
identify it?
(_a_) _By its metallization, through the agency of galvanism._ We are
indebted to _Mr. Sylvester_ for first suggesting the mode by which
galvanic electricity might be applied for the detection of minute
quantities of corrosive sublimate in solution. His method is as follows.
A piece of zinc or iron wire, about three inches in length, is to be
twice bent at right angles, so as to resemble the greek letter π, the
two legs of this figure should be distant about the diameter of a common
wedding ring from each other, and the two ends of the bent wire must
afterwards be tied to a ring of this description. Let a plate of glass,
not less than three inches square, be laid as nearly horizontal as
possible, and on one side drop some sulphuric acid, diluted with about
six times its weight of water, till it spreads to the size of a
halfpenny. At a little distance from this, towards the other side, next
drop some of the solution supposed to contain corrosive sublimate, till
the edges of the two liquids become joined; and let the wire and ring,
prepared as above, be laid in such a way, that the wire may touch the
acid, while the gold ring is in contact with the suspected liquid. If
the minutest quantity of corrosive sublimate be present, the ring, in a
few minutes, will be covered with metallic mercury on the part which
touched the fluid.
The above experiment may be beautifully simplified in the following
manner[282]. Drop a small quantity of a solution, supposed to contain
the salt in question, on a piece of gold, and bring into contact a key,
or some piece of iron, so as to form a galvanic circuit; when, if
sublimate be present, the gold will immediately be whitened.
A solution of _nitrate of silver_ will, under similar treatment,
occasion on gold a white precipitate; but as no amalgamation takes
place, it is readily wiped off, and cannot therefore occasion any
fallacy.
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