Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
The term Pyritic Smelting (or pyrite smelting) is thus applied to
that class of practice in which the whole of the heat required in the
smelting zone is obtained by the combustion of the ore or matte charge
itself; it implies the application of the pyritic principle to the
extreme limit, the use of carbonaceous fuel being reduced to a minimum.
Ideal working is to feed unroasted ore or matte, together with the
requisite fluxes, into the blast furnace, and by the action of an
adequate air blast, to burn out part of the sulphur and iron, the
former escaping with the furnace gases, the latter being slagged off,
whilst the copper in the charge is concentrated in the matte product of
the operation.
This type of smelting is conducted at a number of large modern works,
and though up to the present time the use of coke on the charge has
not been entirely eliminated, research and practical experience have
demonstrated that the small quantity which is employed is not utilised
as fuel by combustion in the air blast at the tuyeres, but that it is,
in fact, oxidised in another manner at some considerable height in the
furnace.
_History._—The idea originated with John Holway, of London, who sought
to extend to the smelting of copper the principles so brilliantly
applied by Bessemer to steel manufacture, and who, in a work which
was published in 1879, suggested and demonstrated the process of
utilising the heat of oxidation of the iron and sulphur constituents of
copper-bearing materials for the smelting and extraction of the copper.
That work is to-day recognised as one of the most masterly expositions
of the principles underlying pyritic smelting and converting, and many
of the most important and recent developments in these branches of
work are proceeding on lines forecasted by him. Holway’s experiments,
conducted on a considerable scale, proved the feasibility of the
principles underlying the process, which was to prepare metallic copper
from sulphide ores in one combined series of operations in a single
furnace unit. Owing, however, to mechanical troubles and difficulties
of operation, as well as to the ultimate withdrawal of financial
support, he was unable to carry the process to a commercial success,
and the single-stage process is at present regarded as being beset by
almost insuperable difficulties, although the latest phases in modern
practice are tending towards a realisation of Holway’s scheme of
working. His paper and published results deserve the closest study.
Public-domain text, read in full here on John Shaqi.
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