Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
Ores suitable for true pyritic smelting are not commonly met with
in practice, and the presence of earthy bases other than iron is
not desirable. Whilst the advantages of polybasic slags from the
point of view of reduced formation temperature, increased fusibility
and liquidity are very marked in ordinary smelting practice, their
presence is not so advantageous in true pyritic smelting, since they
consume silica which is required for the iron oxide at the instant
of formation, and thus tend to decrease the speed of oxidation and
concentration. Polybasic slags have a lower formation temperature, and
in consequence the production of the highly ferruginous slags of high
formation temperature which it is desired to make by the oxidation
of as much iron as possible is retarded. In addition, the presence
of other earthy bases in the charge dilutes its fuel value; they may
even consume valuable heat by requiring decomposition, as in the case
of carbonates. These considerations are not so important in partial
pyritic smelting, where the required heat balance can be adjusted by
coke.
_The Advantages of Pyritic Smelting._
(1) The possibility of direct and immediate treatment of highly pyritic
raw ore in the blast furnace, thus saving all the costs of preliminary
treatment and handling.
(2) The saving of the costs of roasting heavy sulphides.
In former smelting practice, high sulphide contents in a copper ore
were particularly disadvantageous, since the higher the sulphur
contents of the charge the lower was the grade of the resulting matte,
when smelted directly in the blast furnace. In consequence, the higher
sulphur content necessitated a more complete roasting of the ore in
order to ensure a high-grade matte on smelting.
With pyritic smelting the conditions are completely reversed, and
the charge becomes more suitable for direct furnace treatment as its
sulphide contents increase, so that the most suitable ores for pyritic
smelting are those in which the greatest saving is effected by their
not requiring a preliminary roasting operation.
As has been already indicated, this saving includes labour, plant,
handling, time, and interest on capital tied up in the roast yards, as
well as the avoiding of all the mechanical and other losses connected
with such preliminary treatment. Thus at Ducktown, Tennessee, the
material economies effected by the substitution of pyritic smelting for
the processes involving preliminary roasting amounted to no less than
3 to 4 cents per pound of copper produced, in addition to the later
advantages derived from the recovery of values from the gases, and from
the improved conditions of life in the district.
(3) The cost of coke is saved.
Public-domain text, read in full here on John Shaqi.
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