Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
The successful operating of the basic-lined converter on the large
scale and under the conditions of working at great modern plants
was first established by Smith and Pierce at the Baltimore Copper
Company’s Smelter, and the method has since been installed and worked
with success at Garfield, Utah (five converters in operation, one in
reserve); at Perth Amboy, N.J.; at the Washoe Smelter at Anaconda—where
the whole plant is being adapted for basic-converting—and at several
other works.
A recent and promising development has been the reported successful
blowing of fine siliceous concentrates through the tuyeres of
converters at the Garfield Smelter, a method by which it might be
possible to effect the rapid and efficient extraction of values from
fine material otherwise difficult to deal with, affording at the same
time a means of conveniently supplying siliceous flux in a manner
possessing many advantages.
=Principles of the Bessemerising Process.=—The principles underlying
the converter process are those which form the basis of pyritic
smelting practice—of which bessemerising is but a phase. The reactions
involve the very rapid oxidation of iron and sulphur under practically
ideal conditions, and the fluxing by silica of the iron oxide so
produced. The heat of oxidation keeps the materials in a thoroughly
molten state, and maintains the temperature well above that required
for slag formation and perfect fluidity. The heat derived by the
combination of oxygen with the iron and sulphur and that of the iron
oxide with silica is developed so rapidly and in such quantity, owing
to the large masses now worked with, as to cause a reaction-activity
sufficient to make the process independent of heat from external
sources.
It will be noted how markedly the more recent developments of copper
smelting have taken advantage of the factors of the _time element_ and
_mass influence_ in obtaining enormous heat intensities and consequent
high temperatures, by conducting oxidation of sulphides as rapidly and
in as large mass as possible. The same absolute quantities of heat per
unit weight of charge were liberated in the older smelting methods
involving roasting, but the more leisurely manner of operating allowed
the dissipation and dispersion of much of this heat, thus necessitating
the employment of supplementary carbonaceous fuel.
=The Converter.=—The converter is a lined steel vessel in which the
molten matte is contained, and which allows of air being blown through
the material by means of tuyeres which pass through the walls.
The early form of converter was bottom-blown, and similar to that
invented by Bessemer, but it was not successful in operation on the
small quantities of copper matte worked with, owing to the chilling
effect of the cold air on the copper, which, when produced, sank to the
bottom and set above the tuyeres, stopping the air blast, and causing
much loss of metal in the slag.
Public-domain text, read in full here on John Shaqi.
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