Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
The vital requirements in modern converter practice are permanence
of the lining and efficient means of effecting the fluxing of the
iron oxide produced in the converting operation. The necessity for
the frequent relining of converters involves not only heavy direct
expenses, but it occasions waste of heat in the old linings, waste of
material, loss of time, interruption of the processes, liabilities to
outbreaks from the converters, and necessitates much heavy machinery
for the conveying of vessels for relining, as well as large capital
outlay in relining shops, plant, and appliances. In consequence, the
employment of siliceous lining material as flux is usually a most
expensive method of supplying the requisite silica; and so much is this
the case, that an arbitrary limit to the iron contents of the matte has
been rendered necessary, in order to prevent too much of the lining
material being used up at a single blow. It was found cheaper to use
other means of concentrating low-grade matte to a suitable grade for
bessemerising—_i.e._, to flux off the excess of iron by means of silica
in the blast-or the reverberatory-furnace processes.
_Siliceous Linings._—Until recently, the only method for fluxing the
iron in bessemerising, found practicable on a commercial scale, has
been by the destruction of the siliceous lining, minimising the dead
losses as much as possible by employing for the purpose siliceous
materials from which values in the form of gold, silver, or copper
could be simultaneously extracted and collected in the products of the
operation.
Numerous attempts were made to effect combination of the iron oxides
with silica introduced by some other method, but none met with success.
Manhès blew sand through the tuyeres, and obtained as result a spongy
unfused mass in the converter—whilst silica introduced in the form
of lumps rose to the surface unchanged. In each case what silica was
required for flux, was taken up from the siliceous lining. Experiments
of a similar nature, in which basic linings were worked with, resulted
in the fluxing silica being unabsorbed as before, whilst the iron
which was in process of oxidation, not finding a suitable flux, became
super-oxidised, resulting in the production of very infusible masses
of magnetic or ferric oxides which rendered the process unworkable.
Baggaley and others in Montana devoted much attention to experiments on
different methods for introducing silica which would flux successfully,
methods such as superheating or introducing silica held in suspension
in fused silicates being tried, but without marked success, and for
many years siliceous linings were necessarily worked with.
Public-domain text, read in full here on John Shaqi.
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