Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
The copper itself is deposited from the electrolyte on to the
cathode-sheets by the action of the current, whilst at the anodes,
the metal passes into solution, and the other constituents are
either dissolved or precipitated. It follows that in an undisturbed
solution, the liquid near to the cathode becomes gradually impoverished
in copper, resulting in a decrease in the rate of deposition and
necessitating greater electrical pressure, whilst in the neighbourhood
of the anode, the liquor is proportionately stronger in copper and
less acid in character. Should these conditions continue to any great
extent, the working of the bath is seriously interfered with, since
diffusion proceeds too slowly for uniformity to be restored, and
in order to secure uniform composition of the electrolyte, it must
be maintained in gentle motion by some system of circulation. This
agitation and mixing is assisted by the aëration of the bath for the
purpose of hastening the oxidation and precipitation of several of the
impurities—this being effected by blowing through the liquid a gentle
supply of air.
_Temperature._—The electrical resistance of the solution decreases as
the temperature rises, and in practice the bath is maintained at a
uniform temperature of 45° to 50° C. By this means a useful increase in
conductivity is obtained, the strength of the deposited copper being at
the same time greatly augmented.
_Electrical Conditions._—The electrical factors which mainly control
the working of the electrolytic process are those of—
(_a_) Current density.
(_b_) Voltage.
(_a_) _Current Density._—The quantity of metal deposited from an
electrolyte is proportional to the current which passes, and to the
electro-chemical equivalent of the particular metal. Thus a current of
one ampere will deposit from copper sulphate solution, 1·1832 grammes
of copper per hour, and the total quantity deposited in any given
time is determined by the product of the current, the time, and this
electro-chemical equivalent (which is determined experimentally).
In practical operation, a factor which is amongst the most important
of those governing the working of a plant, is the current density,
or current per unit of area of depositing surface, since from this
factor the rate of deposition upon the cathode plates is determined,
and from it the power requirements, accommodation, etc., for the
plant are fixed. The current density is subject to wide variation,
but, as a general rule, it ranges from 8 to 18 amperes per square
foot of plate-area. Its value is largely dependent upon the speed of
working, the cost of power, and the composition of the anode metal, the
electrolyte and the desired product, etc.
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