Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
In general, high current-density possesses many advantages, resulting
from the fact that it occasions a more rapid deposition. It causes a
proportionately greater output, consequently the stock of metal held
back in the tanks is reduced, and hence there is less capital locked
up in the form of metal undergoing treatment, and less plant and
accommodation are required for the same output.
The current density permissible is, however, limited by the composition
of the electrodes and the solution. High current-density causes rapid
dissolution of the anodes, and if the plates are not particularly
free from impurity, the electrolyte rapidly becomes contaminated,
since its dissolving power on the impurities becomes greater with
increased electrolytic action, and this affords less opportunity for
the precipitation and settling of the injurious constituents. In
consequence, the cathode copper is contaminated through this mechanical
inclusion of impurities, whilst electro-deposition of some of these
materials may also be encouraged. The presence of much silver in the
anodes causes the rapid breaking-up of the plates, especially if the
current density be high, and thus the separation of the values in the
slimes is not so efficiently managed. With high values in the anode
copper, it is necessary to reduce the current density to 8 or 10
amperes per square foot, whereas with purer metal a density of as much
as 16 to 20 may be conveniently employed.
(_b_) _Voltage._—Electrical pressure is required in order to force the
depositing current through the electrolyte against the resistances in
the circuit. The voltage required depends upon the current density,
the composition and temperature of the electrolyte, the composition
of the anodes, and also upon the general conditions of working. These
being constant, the voltage necessary is largely a factor of the number
of electrodes in series in the tank and of the distance apart of the
plates. Under ordinary circumstances this voltage varies from 0·1 to
about 0·3 volt. High voltage is to be avoided, owing to the danger of
short-circuiting, especially in cases where the accumulation of mud in
the tanks, or the impregnation of metallic salts in the tank walls, or
the growth of excrescences upon the plates, lead to the passage of the
current through these conductors rather than through the electrolyte
solution itself. Short circuiting naturally diminishes the output of
the plant.
These electrical factors which form the basis of the power requirements
of the refinery, call for careful observation during the progress
of the operations in order to ensure successful working and a high
efficiency of the plant.
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