Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
The cathodes are placed in a second rack, and likewise brought into
position, between the anodes. The solution is then turned into the
tank, the current started, and the refining proceeds, with a steady
flow of liquid circulating through the system. The operations of
changing electrodes, cleaning and reloading occupy about one hour,
and, but for this manipulation, the process under normal working is
continuous. In ordinary practice, about 20 to 25 lbs. of copper are
deposited daily on each cathode. Constant examination is made as to the
electrical conditions, and the composition, temperature, and density of
the solutions.
The anodes usually remain in the bath for a period of about six weeks,
and they are then removed from the tank, scrubbed, and sent back to the
furnaces to be remelted and re-cast into fresh anodes, the quantity of
such anode scrap under good working conditions amounting to about 9 or
10 per cent. of the original metal.
[Illustration: Fig. 75.—Tank-house, showing Anode Crane (Ulke).]
The cathodes remain in the tanks for about one week, by which time a
deposit of from 150 to 170 lbs. of pure metal has been obtained upon
each. The practice of frequently replacing the cathodes possesses,
among other advantages, those of maintaining a more even current
density over the plates, of preventing the growth of excrescences and
the irregular dissolution of the anodes, and of lessening the danger
of breakdown of the somewhat slenderly suspended cathodes, by putting
less weight on the supports. The removal in one operation of the entire
batch of cathodes from the bath is effected by means of the suspended
hook-frame, as employed in charging. The plates are rinsed, the top
edges are cut off and returned with the anode scrap, whilst the pure
electrolytic copper passes to the refining and casting furnaces, where
it is prepared for the market.
_Collection of the Slimes._—Depending upon the working conditions
of the refinery, but usually at intervals of three months, the
precipitated slimes are collected and the tanks are cleaned out. The
quantity of slime deposited is generally not very large, from 15 to 25
lbs. per tank being a not unusual yield. The current and the supply
of solution are cut off, the plates removed, the contents of the tank
allowed to settle, the liquid siphoned off to within about 6 inches
of the bottom, and the residues are swilled out through a trap at the
bottom of the tank. The sludge passes through a sieve that separates
the lumps of anode copper which have broken off and fallen to the
bottom of the tank, the slime then passes to the special refinery for
treatment. The processes adopted for recovering the gold and silver
from this residue are highly specialised, and belong properly to the
technology of refining of the precious metals.
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