Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
Table III. on preceding page, summarises the results of the work of
Addicks and Johnson, and indicates the effects of small amounts of
different impurities on the conductivity of the metal.
The notoriously destructive effect of arsenic on the conductivity is
very apparent.
The influence of most of the common impurities is of a similar nature,
and detailed investigations indicate that the effect is more or less
progressive as the quantity increases—within the limits usually present
in commercial metal. The results of Hiorns and Lamb’s experiments with
reference to arsenic and antimony are indicated in Fig. 4.
The _specific gravity_ of copper naturally varies according to its
condition and composition. When pure and in the worked state, its
density is 8·95; cast metal, more open and inclined to porosity, has a
density of about 8·2 to 8·6, depending on the purity, rate of cooling,
etc. Impurities lower the specific gravity.
The _conductivity for heat_ of the metal is high, being 898 compared
with gold as 1,000, and as a conductor it is two and a-half times more
efficient than iron. It is this property, combined with its toughness
and resistance to corrosion, etc., which largely determines its
employment for heaters, steam-coils, and the like.
[Illustration: Fig. 4.—Influence of Arsenic and Antimony on the
Electrical Conductivity of Copper.]
_Power of Dissolving Gases._—When molten, especially under reducing
conditions, the metal possesses the property, common to many others,
of absorbing gases such as carbon monoxide, hydrogen, hydrocarbons,
sulphur dioxide, etc., which are moreover, to a large extent insoluble
in the solid material, and are, therefore, often liberated at or about
the moment of solidification; though some may remain dissolved. This
action is one of the causes of the difficulty which is experienced
in making sound castings of the metal, particularly since the gases
mentioned are present in quantity during the poling and refining
operations. The presence of certain materials in the copper, as in
the case of steel, appears to reduce the dissolving power of the
liquid metal for these gases, or possibly to increase their solubility
when the copper is solidifying, and in this way tends to minimise
their injurious effects. It would seem that one of the functions of
the cuprous oxide, which is purposely introduced into the metal when
“bringing it up to pitch,” is to exert this action. The ridge in the
ingot of overpoled copper is, to some extent, accounted for as being
due to the effects of the evolved gases, and this appearance indicates
the absence of the requisite quantity of cuprous oxide necessary to
counteract the effect.
Copper is also supposed to be capable of holding certain quantities
of gas in solution after it has become solid, and the resulting
metal is more brittle and often commercially useless. Several of the
characteristics of overpoled copper probably arise from this cause also.
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