Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
=Impurities[2] in Copper.=—In view of the marked influence of
impurities on the properties of metallic copper, it may be advisable in
this place briefly to review the results of recent scientific work as
to the condition in which they exist in the metal, thus offering some
clearer indication of the manner in which they affect the mechanical
and other properties. The common impurities in ordinary commercial
metal may be oxygen, arsenic, antimony, bismuth, lead, and to smaller
extents, iron, sulphur, tellurium, and selenium.
A factor of much importance is that the effect of two or more of the
common constituents when present together, may be of even greater
moment than that of each one separately, and in this connection
Hampe’s classical work should be consulted. The investigation of the
joint effects of impurities becomes so complex that systematic study
progresses but slowly. Metallographic work is, however, revealing
much evidence, and the researches in progress at present at several
laboratories will, when published, afford greatly increased knowledge
on the subject. Recent papers by F. Johnson give valuable detailed
information (see References, p. 34). The importance of oxygen in this
connection is particularly marked: its effects are profound, since in
addition to its own specific influence as oxide, it also brings about
chemical changes in some of the other constituents, thus leading to
the formation of entirely new compounds possessing quite different
properties. The beneficial influence of certain definite proportions
of oxygen in addition to the other constituents of commercial copper
is well known in practice, and has been systematically studied by
Hampe, and later by several other workers with more delicate means of
investigation at their disposal.
_Oxygen in Copper._—Molten copper has the power of dissolving its
oxide, Cu_{2}O. When the melted metal is exposed to oxygen, this oxide
is produced and passes into solution in the liquid, yielding a series
of binary alloys, of which the oxide acts as the second constituent.
The equilibrium diagram of the series, as worked out by Heyn[3] (see
Fig. 5), affords a good indication of these relationships, and throws
light on several features connected with the presence of oxygen in
copper.
[Illustration: Fig. 5.—Relations of Copper and Oxygen.]
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