Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
Tensile strength is reduced on annealing, but never to so low a
degree as that of the cast material, the usual figure being 12 to 14
tons per square inch. The effect of temperature in reducing tensile
strength, especially when impurities are present, is important from the
industrial point of view. The reduction in strength caused by annealing
appears to be considerably smaller in the presence of arsenic and
antimony.
Arsenic increases the tensile strength of copper when the metal
is of the correct pitch, generally to well over 15 or 16 tons,
in the presence of the proportions usually found. Antimony has a
similar effect. Some workers state that, within certain limits, the
strengthening effect of this element is even more pronounced. Excess
of antimony exerts, however, a much more adverse influence than does
excess of arsenic. The elongation is increased by the presence of
moderate quantities of arsenic.
Oxygen _per se_, when present in moderate quantity in copper, has but
little effect on the tenacity. Bismuth, tellurium, sulphur, and lead
are the impurities which lower the strength, even when present in
minute quantities, and especially on heating. Bismuth in the proportion
of 0·005 per cent. lowers the malleability and ductility considerably,
and recent reports state that 0·02 per cent. bismuth renders copper
cold short, that 0·05 per cent. makes it red short, and that 0·005
per cent. is the limit for electrolytic copper which is to be rolled.
The deleterious effects of bismuth are, as already explained, to some
extent masked by the presence of arsenic and by oxygen.
The strength is increased by the presence of nickel, tin, and zinc in
the proportions usually present in the commercial metal; these are,
however, generally small.
From the foregoing review, indications will be afforded of the reasons
for the choice by engineers of “tough-pitch” copper for much of their
work, and the explanation for the 0·3 to 0·5 per cent. arsenic often
particularly specified for. The frequent use of arsenical coppers for
such purposes as fire-box plates will also be understood, since the
arsenic not only improves the mechanical properties of the metal, but
ensures the retention of rigidity and strength at the high working
temperatures required, to a greater degree than would have been the
case had pure copper been employed.
The effect of the above factors on the elastic limit of copper, is
also very marked and of much importance, the influence being closely
analogous to that produced on the other mechanical properties.
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